0000000001304902
AUTHOR
Kousik Ghosh
Synthesis, structure and magnetic characterization of a dinuclear and two mononuclear iron(III) complexes with N,O-donor Schiff base ligands
Abstract One centrosymmetric dinuclear and two mononuclear iron(III) Schiff base complexes, [(µ-OMe)2Fe2(L1)2(N3)2] (1) {HL1 = 2-((2-(dimethylamino)ethylimino)methyl)-6-ethoxyphenol}, [FeL2(OH2)(N3)]·CH3OH (2) {H2L2 = N,N′-bis(3-ethoxysalicylidene)propane-1,3-diamine} and [FeL3(OH2)(NCS)]·2H2O (3) {H2L3 = N,N′-bis(3-methoxysalicylidene)propane-1,3-diamine}, have been synthesized and characterized by elemental analysis and spectral studies. X-ray diffraction analysis was used to determine the structures of all three complexes. Variable temperature (2–300 K) magnetic susceptibility (χ) data of complex 1 show that both iron(III) centres in the complex are in a high spin configuration (S = 5/2)…
CCDC 1812958: Experimental Crystal Structure Determination
Related Article: Tanmoy Basak, Kousik Ghosh, Carlos J. Gómez-García, Shouvik Chattopadhyay|2018|Polyhedron|146|42|doi:10.1016/j.poly.2017.12.040
CCDC 1812959: Experimental Crystal Structure Determination
Related Article: Tanmoy Basak, Kousik Ghosh, Carlos J. Gómez-García, Shouvik Chattopadhyay|2018|Polyhedron|146|42|doi:10.1016/j.poly.2017.12.040
CCDC 1579669: Experimental Crystal Structure Determination
Related Article: Tanmoy Basak, Kousik Ghosh, Carlos J. Gómez-García, Shouvik Chattopadhyay|2018|Polyhedron|146|42|doi:10.1016/j.poly.2017.12.040