Author: Niklas Bormann

0000000001304913

AUTHOR

Niklas Bormann

showing 3 related works from this author

Synthesis of N‐Monosubstituted Sulfondiimines by Metal‐free Iminations of Sulfiliminium Salts

2023

Sulfondiimines are marginalized entities among nitrogencontaining organosulfur compounds, despite offering promising properties for applications in various fields including medicinal and agrochemical. Herein, we present a metal-free and rapid synthetic procedure for the synthesis of N-monosubstituted sulfondiimines that overcomes current limitations in their synthetic accessibility. Particularly, S,S-dialkyl substrates, which are commonly difficult to convert by existing methods, react well with a combination of iodine, 1,8-diazabicyclo[5.4.0]undec-7-en (DBU), and iminoiodanes (PhINR) in acetonitrile (MeCN) to furnish the corresponding sulfondiimines in yields up to 85% (25 examples). Valua…

kemiallinen synteesiiodineGeneral MedicineGeneral ChemistryrikkiCatalysisjodilääkekemiamedicinal chemistrysulfuriminationtyppiyhdisteetnitrenesulfondiimineorgaaniset yhdisteet

researchProduct

CCDC 2242257: Experimental Crystal Structure Determination

2023

Related Article: Marco T. Passia, Niklas Bormann, Jas S. Ward, Kari Rissanen, Carsten Bolm|2023|Angew.Chem.,Int.Ed.|62||doi:10.1002/anie.202305703

Space GroupCrystallographyCrystal SystemCrystal StructureN-[diethyl(imino)-sulfanylidene]-4-nitrobenzene-1-sulfonamideeCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 2242258: Experimental Crystal Structure Determination

2023

Related Article: Marco T. Passia, Niklas Bormann, Jas S. Ward, Kari Rissanen, Carsten Bolm|2023|Angew.Chem.,Int.Ed.|62||doi:10.1002/anie.202305703

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(234678910-octahydro-1H-pyrimido[12-a]azepin-5-ium) iodide triiodide iodineExperimental 3D Coordinates

researchProduct

PEPhysical Sciences and Engineering
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