0000000001305056
AUTHOR
Vicente Pérez-mondéjar
A water molecule in the interior of a 1H-pyrazole Cu2+ metallocage
Water has a great tendency to associate through hydrogen bonding with water molecules or other hydrogen bond donor or acceptor groups. Here the case of a water molecule encapsulated in the interior of a metallocage receptor is presented. The association of four copper(II) ions and two aza-macrocyclic receptors in which two 1H-pyrazole units are connected by cadaverine diamines leads to the inclusion of a water molecule into the cage, as proved by X-ray analysis and infrared spectroscopy. The included water molecule shows no hydrogen bonding with any component of the cage presenting only a weak hydrogen bond with an oxygen atom of a perchlorate counter-anion. The IR stretching vibrations pre…
CCDC 1468808: Experimental Crystal Structure Determination
Related Article: Javier Pitarch-Jarque, Raquel Belda, Salvador Blasco, Pilar Navarro, Roberto Tejero, José Miguel Junquera-Hernández, Vicente Pérez-Mondéjar, Enrique García-España|2016|New J.Chem.|40|5670|doi:10.1039/C5NJ03234B
CCDC 892312: Experimental Crystal Structure Determination
Related Article: Javier Pitarch-Jarque, Raquel Belda, Salvador Blasco, Pilar Navarro, Roberto Tejero, José Miguel Junquera-Hernández, Vicente Pérez-Mondéjar, Enrique García-España|2016|New J.Chem.|40|5670|doi:10.1039/C5NJ03234B
CCDC 1468807: Experimental Crystal Structure Determination
Related Article: Javier Pitarch-Jarque, Raquel Belda, Salvador Blasco, Pilar Navarro, Roberto Tejero, José Miguel Junquera-Hernández, Vicente Pérez-Mondéjar, Enrique García-España|2016|New J.Chem.|40|5670|doi:10.1039/C5NJ03234B
CCDC 892315: Experimental Crystal Structure Determination
Related Article: Javier Pitarch-Jarque, Raquel Belda, Salvador Blasco, Pilar Navarro, Roberto Tejero, José Miguel Junquera-Hernández, Vicente Pérez-Mondéjar, Enrique García-España|2016|New J.Chem.|40|5670|doi:10.1039/C5NJ03234B
CCDC 892316: Experimental Crystal Structure Determination
Related Article: Javier Pitarch-Jarque, Raquel Belda, Salvador Blasco, Pilar Navarro, Roberto Tejero, José Miguel Junquera-Hernández, Vicente Pérez-Mondéjar, Enrique García-España|2016|New J.Chem.|40|5670|doi:10.1039/C5NJ03234B