Author: G. De Robillard

0000000001305351

AUTHOR

G. De Robillard

showing 3 related works from this author

Bio-based 1,3-diisobutyl imidazolium hydrogen oxalate [iBu 2 IM](HC 2 O 4 ) as CO 2 shuttle

2017

International audience; This manuscript describes the using of biosourced L-valine, oxalic acid and glyoxal to produce a biobased imidazolium hydrogen oxalate [iBu(2)IM](HC2O4) which is converted to its related hydrogen carbonate salt by a simple electrolysis without using strong base. The addition of weak protic acids to the latter compound leads to a rapid and quantitative CO2 release with formation of the starting hydrogen oxalate salt or a new halide free bio-based ionic liquid [iBu(2)IM](AcO) which is able to adsorb reversibly the CO2 at room temperature. The protonation reactions, combined with electrolysis, could then be a promising alternative solution for storage and transport of C…

HydrogenOxalic acidInorganic chemistryHalideSalt (chemistry)chemistry.chemical_elementProtonation010402 general chemistrycarbon-dioxide01 natural sciences[ CHIM ] Chemical SciencesOxalatelaw.inventionefficientionic liquidschemistry.chemical_compoundlawstabilized phosphenium adductsEnvironmental Chemistry[CHIM]Chemical Scienceselectrochemical reductioncaptureacidsmethanolchemistry.chemical_classificationElectrolysis010405 organic chemistrycrystal-structurePollution0104 chemical scienceschemistrydimethyl-sulfoxideIonic liquid

researchProduct

CCDC 1560697: Experimental Crystal Structure Determination

2017

Related Article: G. de Robillard, A. H. Fournier, H. Cattey, C. H. Devillers, J. Andrieu|2017|Green Chemistry|19|4912|doi:10.1039/C7GC02167D

13-bis(2-methylpropyl)-1H-imidazol-3-ium hydrogen oxalateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1560698: Experimental Crystal Structure Determination

2017

Related Article: G. de Robillard, A. H. Fournier, H. Cattey, C. H. Devillers, J. Andrieu|2017|Green Chemistry|19|4912|doi:10.1039/C7GC02167D

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters13-bis(2-methylpropyl)-1H-imidazol-3-ium hydrogen carbonateExperimental 3D Coordinates

researchProduct

PEPhysical Sciences and Engineering
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