0000000001305648

AUTHOR

Mario L. Naitana

showing 9 related works from this author

Surface Acoustic Wave Sensors for the Detection of Hazardous Compounds in Indoor Air

2017

Presented at the Eurosensors 2017 Conference, Paris, France, 3–6 September 2017.; International audience; In this work, the authors show the capabilities of Surface Acoustic Wave (SAW) devices coupled with various absorbents to probe the properties of gas sensitive materials for the manufacturing of hazardous gas sensors. The great capabilities of cobalt corroles for the trapping of carbon monoxide (CO) were exploited to produce selective sensors. These corroles were deposited on SAW delay lines surfaces and then exposed to carbon monoxide (CO) in standard conditions. Concentrations of a few hundreds of ppb were measured emphasizing the interest of such sensors for the detection of CO. Anot…

Materials scienceSAWIndoor airchemistry.chemical_elementlcsh:ANanotechnologyTrapping010402 general chemistry01 natural sciencescarbon monoxidechemistry.chemical_compoundHazardous wastePorositySurface acoustic wave[CHIM.MATE]Chemical Sciences/Material chemistry06 humanities and the artsNano-porous films060202 literary studies0104 chemical sciencescobalt corroleschemistry[ CHIM.MATE ] Chemical Sciences/Material chemistry0602 languages and literatureformaldehydeSurface acoustic wave sensorlcsh:General WorksCobaltLove wavesCarbon monoxideProceedings of Eurosensors 2017, Paris, France, 3–6 September 2017
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Synthesis, Characterization, and Electrochemistry of Open-Chain Pentapyrroles and Sapphyrins with Highly Electron-Withdrawing meso -Tetraaryl Substit…

2017

International audience; A series of open-chain pentapyrroles and sapphyrins with highly electron-withdrawing substituents (i.e., CN, CF3 , or CO2 Me) on the meso-phenyl rings was synthesized and characterized as to the spectral properties, protonation reactions, and electrochemistry in non-aqueous media. The investigated compounds are represented as (Ar)4 PPyH3 and (Ar)4 SapH3 where PPy and Sap correspond to the tri-anion of the open-chain pentapyrrole and sapphyrin, respectively, and Ar=p-CNPh, p-CF3 Ph, or p-CO2 MePh. UV/Vis and 1 H NMR spectroscopy as well as mass spectrometry data are given for the confirmation of the structures for the newly synthesized compounds. An X-ray structure fo…

Absorption spectroscopyprotonationInorganic chemistryporphyrinoidsProtonationpentapyrroles010402 general chemistry01 natural sciencesRedox[ CHIM ] Chemical SciencesCatalysischemistry.chemical_compound[SPI]Engineering Sciences [physics]PyridinePolymer chemistryTrifluoroacetic acid[CHIM]Chemical SciencesEquilibrium constantsapphyrins010405 organic chemistryOrganic ChemistryGeneral Chemistry0104 chemical scienceschemistryelectrochemistryProton NMRCyclic voltammetry
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The Difficult Marriage of Triarylcorroles with Zinc and Nickel Ions.

2022

The coordination chemistry of corrole has witnessed a great improvement in the past few years and its Periodic Table has been widened to be so large that it is compared with that of porphyrins. However, Ni and Zn ions, commonly used with porphyrins for both synthetic and theoretical purposes, are sparsely reported in the case of corroles. Here, we report synthetic protocols for preparing Ni and Zn triarylcorrole complexes. In the case of Zn, the preliminary oxidation of the free base corrole in DMSO to the neutral corrole radical is a necessary step to obtain the coordination of the metal ion, because the direct reaction led to the formation of an open-chain tetrapyrrole. The Ni complex cou…

Inorganic ChemistryIonskemiallinen synteesiaromaattiset yhdisteetZincsinkki (metallit)PorphyrinsNickelSettore CHIM/07Dimethyl SulfoxidekompleksiyhdisteetPhysical and Theoretical ChemistrynikkeliInorganic chemistry
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CCDC 1539258: Experimental Crystal Structure Determination

2017

Related Article: Wenqian Shan, Nicolas Desbois, Virginie Blondeau-Patissier, Mario L. Naitana, Valentin Quesneau, Yoann Rousselin, Claude P. Gros, Zhongping Ou, Karl M. Kadish|2017|Chem.-Eur.J.|23|12833|doi:10.1002/chem.201701968

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters5101520-tetrakis(4-(trifluoromethyl)phenyl)pentapyrrin chloroform solvateExperimental 3D Coordinates
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CCDC 1578032: Experimental Crystal Structure Determination

2018

Related Article: Xiaoqin Jiang, Mario L. Naitana, Nicolas Desbois, Valentin Quesneau, Stéphane Brandès, Yoann Rousselin, Wenqian Shan, W. Ryan Osterloh, Virginie Blondeau-Patissier, Claude P. Gros, Karl M. Kadish|2018|Inorg.Chem.|57|1226|doi:10.1021/acs.inorgchem.7b02655

Space GroupCrystallographyCrystal System(10-(4-fluoro-3-nitrophenyl)-515-dimesitylcorrolato)-bis(pyridine)-cobalt(iii) cyclohexane tetrahydrofuran solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1812155: Experimental Crystal Structure Determination

2018

Related Article: Valentin Quesneau, Wenqian Shan, Nicolas Desbois, Stephane Brandes, Yoann Rousselin, Meddy Vanotti, Virginie Blondeau-Patissier, Mario Naitana, Paul Fleurat-Lessard, Eric Van Caemelbecke, Karl M. Kadish, Claude P. Gros|2018|Eur.J.Inorg.Chem.|2018|4265|doi:10.1002/ejic.201800897

Space GroupCrystallographyCrystal SystemCrystal Structurediammine-(51015-tris(26-dichlorophenyl)corrolato)-cobalt(iii) n-hexane solvateCell ParametersExperimental 3D Coordinates
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CCDC 1554869: Experimental Crystal Structure Determination

2019

Related Article: Wenqian Shan, Valentin Quesneau, Nicolas Desbois, Virginie Blondeau-Patissier, Mario L. Naitana, Yoann Rousselin, Claude P. Gros, Zhongping Ou, Karl M. Kadish|2019|J.Porphyrins Phthalocyanines|23|213|doi:10.1142/S1088424619500214

25-bis((4-bromophenyl)(5-((4-bromophenyl)pyrrol-2-ylmethylidene)pyrrol-2-yl)methylene)pyrrole chloroform solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2194501: Experimental Crystal Structure Determination

2022

Related Article: Mario L. Naitana, W. Ryan Osterloh, Lorena Di Zazzo, Sara Nardis, Fabrizio Caroleo, Pierluigi Stipa, Khai-Nghi Truong, Kari Rissanen, Yuanyuan Fang, Karl M. Kadish, Roberto Paolesse|2022|Inorg.Chem.|61|17790|doi:10.1021/acs.inorgchem.2c03099

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates5-[{5'-[(5-benzoyl-1H-pyrrol-2-yl)(phenyl)methylidene]-1H5'H-[22'-bipyrrol]-5-yl}(phenyl)methylidene]-15-dihydro-2H-pyrrol-2-one
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CCDC 1815709: Experimental Crystal Structure Determination

2018

Related Article: Valentin Quesneau, Wenqian Shan, Nicolas Desbois, Stephane Brandes, Yoann Rousselin, Meddy Vanotti, Virginie Blondeau-Patissier, Mario Naitana, Paul Fleurat-Lessard, Eric Van Caemelbecke, Karl M. Kadish, Claude P. Gros|2018|Eur.J.Inorg.Chem.|2018|4265|doi:10.1002/ejic.201800897

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters515-dimesityl-10-(246-trimethoxyphenyl)corrole acetone solvateExperimental 3D Coordinates
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