0000000001305648
AUTHOR
Mario L. Naitana
Surface Acoustic Wave Sensors for the Detection of Hazardous Compounds in Indoor Air
Presented at the Eurosensors 2017 Conference, Paris, France, 3–6 September 2017.; International audience; In this work, the authors show the capabilities of Surface Acoustic Wave (SAW) devices coupled with various absorbents to probe the properties of gas sensitive materials for the manufacturing of hazardous gas sensors. The great capabilities of cobalt corroles for the trapping of carbon monoxide (CO) were exploited to produce selective sensors. These corroles were deposited on SAW delay lines surfaces and then exposed to carbon monoxide (CO) in standard conditions. Concentrations of a few hundreds of ppb were measured emphasizing the interest of such sensors for the detection of CO. Anot…
Synthesis, Characterization, and Electrochemistry of Open-Chain Pentapyrroles and Sapphyrins with Highly Electron-Withdrawing meso -Tetraaryl Substituents
International audience; A series of open-chain pentapyrroles and sapphyrins with highly electron-withdrawing substituents (i.e., CN, CF3 , or CO2 Me) on the meso-phenyl rings was synthesized and characterized as to the spectral properties, protonation reactions, and electrochemistry in non-aqueous media. The investigated compounds are represented as (Ar)4 PPyH3 and (Ar)4 SapH3 where PPy and Sap correspond to the tri-anion of the open-chain pentapyrrole and sapphyrin, respectively, and Ar=p-CNPh, p-CF3 Ph, or p-CO2 MePh. UV/Vis and 1 H NMR spectroscopy as well as mass spectrometry data are given for the confirmation of the structures for the newly synthesized compounds. An X-ray structure fo…
The Difficult Marriage of Triarylcorroles with Zinc and Nickel Ions.
The coordination chemistry of corrole has witnessed a great improvement in the past few years and its Periodic Table has been widened to be so large that it is compared with that of porphyrins. However, Ni and Zn ions, commonly used with porphyrins for both synthetic and theoretical purposes, are sparsely reported in the case of corroles. Here, we report synthetic protocols for preparing Ni and Zn triarylcorrole complexes. In the case of Zn, the preliminary oxidation of the free base corrole in DMSO to the neutral corrole radical is a necessary step to obtain the coordination of the metal ion, because the direct reaction led to the formation of an open-chain tetrapyrrole. The Ni complex cou…
CCDC 1539258: Experimental Crystal Structure Determination
Related Article: Wenqian Shan, Nicolas Desbois, Virginie Blondeau-Patissier, Mario L. Naitana, Valentin Quesneau, Yoann Rousselin, Claude P. Gros, Zhongping Ou, Karl M. Kadish|2017|Chem.-Eur.J.|23|12833|doi:10.1002/chem.201701968
CCDC 1578032: Experimental Crystal Structure Determination
Related Article: Xiaoqin Jiang, Mario L. Naitana, Nicolas Desbois, Valentin Quesneau, Stéphane Brandès, Yoann Rousselin, Wenqian Shan, W. Ryan Osterloh, Virginie Blondeau-Patissier, Claude P. Gros, Karl M. Kadish|2018|Inorg.Chem.|57|1226|doi:10.1021/acs.inorgchem.7b02655
CCDC 1812155: Experimental Crystal Structure Determination
Related Article: Valentin Quesneau, Wenqian Shan, Nicolas Desbois, Stephane Brandes, Yoann Rousselin, Meddy Vanotti, Virginie Blondeau-Patissier, Mario Naitana, Paul Fleurat-Lessard, Eric Van Caemelbecke, Karl M. Kadish, Claude P. Gros|2018|Eur.J.Inorg.Chem.|2018|4265|doi:10.1002/ejic.201800897
CCDC 1554869: Experimental Crystal Structure Determination
Related Article: Wenqian Shan, Valentin Quesneau, Nicolas Desbois, Virginie Blondeau-Patissier, Mario L. Naitana, Yoann Rousselin, Claude P. Gros, Zhongping Ou, Karl M. Kadish|2019|J.Porphyrins Phthalocyanines|23|213|doi:10.1142/S1088424619500214
CCDC 2194501: Experimental Crystal Structure Determination
Related Article: Mario L. Naitana, W. Ryan Osterloh, Lorena Di Zazzo, Sara Nardis, Fabrizio Caroleo, Pierluigi Stipa, Khai-Nghi Truong, Kari Rissanen, Yuanyuan Fang, Karl M. Kadish, Roberto Paolesse|2022|Inorg.Chem.|61|17790|doi:10.1021/acs.inorgchem.2c03099
CCDC 1815709: Experimental Crystal Structure Determination
Related Article: Valentin Quesneau, Wenqian Shan, Nicolas Desbois, Stephane Brandes, Yoann Rousselin, Meddy Vanotti, Virginie Blondeau-Patissier, Mario Naitana, Paul Fleurat-Lessard, Eric Van Caemelbecke, Karl M. Kadish, Claude P. Gros|2018|Eur.J.Inorg.Chem.|2018|4265|doi:10.1002/ejic.201800897