0000000001305668

AUTHOR

Sourav Dey

showing 3 related works from this author

Magneto-Structural Properties and Theoretical Studies of a Family of Simple Heterodinuclear Phenoxide/Alkoxide Bridged MnIIILnIII Complexes : On the …

2018

A family of MnIIILnIII strictly dinuclear complexes of general formula [MnIII(μ-L)(μ-OMe)(NO3)LnIII(NO3)2(MeOH)] (LnIII = Gd, Dy, Er, Ho) has been assembled in a one pot synthesis from a polydentate, multipocket aminobis(phenol)ligand [6,6'-{(2-(1-morpholyl)ethylazanediyl)bis(methylene)}bis(2-methoxy-4-methylphenol)], Mn(NO3)2·4H2O, Ln(NO3)3· nH2O, and NEt3 in MeOH. These compounds represent the first examples of fully structurally and magnetically characterized dinuclear MnIIILnIII complexes. Single X-ray diffraction studies reveal that all complexes are isostructural, consisting of neutral dinuclear molecules where the MnIII and LnIII metal ions, which exhibit distorted octahedral MnN2O4 …

magneettiset ominaisuudet010405 organic chemistryChemistryAb initiokompleksiyhdisteet010402 general chemistry01 natural sciences0104 chemical sciencesInorganic ChemistryMagnetizationMagnetic anisotropyCrystallographyAb initio quantum chemistry methodsAntiferromagnetismMoleculecoordination complexesmagnetic propertiesPhysical and Theoretical ChemistryIsostructuralAnisotropyta116Inorganic Chemistry
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CCDC 1585390: Experimental Crystal Structure Determination

2018

Related Article: Mikko M. Hänninen, Antonio J. Mota, Reijo Sillanpää, Sourav Dey, Gunasekaran Velmurugan, Gopalan Rajaraman, Enrique Colacio|2018|Inorg.Chem.|57|3683|doi:10.1021/acs.inorgchem.7b02917

(mu-22'-[{[2-(morpholin-4-yl)ethyl]azanediyl}bis(methylene)]bis[6-methoxy-4-(prop-2-en-1-yl)phenolato])-(mu-methoxy)-bis(methanol)-tris(nitrato)-erbium(iii)-manganese(ii)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1585387: Experimental Crystal Structure Determination

2018

Related Article: Mikko M. Hänninen, Antonio J. Mota, Reijo Sillanpää, Sourav Dey, Gunasekaran Velmurugan, Gopalan Rajaraman, Enrique Colacio|2018|Inorg.Chem.|57|3683|doi:10.1021/acs.inorgchem.7b02917

Space GroupCrystallographyCrystal System(mu-22'-[{[2-(morpholin-4-yl)ethyl]azanediyl}bis(methylene)]bis[6-methoxy-4-(prop-2-en-1-yl)phenolato])-(mu-methoxy)-bis(methanol)-tris(nitrato)-gadolinium(iii)-manganese(ii)Crystal StructureCell ParametersExperimental 3D Coordinates
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