Author: Eric T. Strand

0000000001305676

AUTHOR

Eric T. Strand

showing 3 related works from this author

Molecule Isomerism Modulates the Diradical Properties of Stable Singlet Diradicaloids

2019

Inclusion of quinoidal cores in conjugated hydrocarbons is a common strategy to modulate the properties of diradicaloids formed by aromaticity recovery within the quinoidal unit. Here we describe an alternative approach of tuning of diradical properties in indenoindenodibenzothiophenes upon anti → syn isomerism of the benzothiophene motif. This alters the relationship of the S atom with the radical center from linear to cross conjugation yet retains the same 2,6-naphtho conjugation pattern of the rearomatized core. We conduct a full comparison between the anti and syn derivatives based on structural, spectroscopic, theoretical, and magnetic measurements, showing that these systems are stabl…

ChemistryDiradicalBenzothiopheneAromaticityGeneral ChemistryConjugated system010402 general chemistryPhotochemistry01 natural sciencesBiochemistryCatalysis0104 chemical scienceschemistry.chemical_compoundColloid and Surface ChemistryMoleculeSinglet stateCross-conjugationTriplet stateJournal of the American Chemical Society

researchProduct

CCDC 1949404: Experimental Crystal Structure Determination

2020

Related Article: Joshua E. Barker, Justin J. Dressler, Abel Cárdenas Valdivia, Ryohei Kishi, Eric T. Strand, Lev N. Zakharov, Samantha N. MacMillan, Carlos J. Gómez-García, Masayoshi Nakano, Juan Casado, Michael M. Haley|2019|J.Am.Chem.Soc.|142|1548|doi:10.1021/jacs.9b11898

614-bis(4-t-butyl-26-dimethylphenyl)[1]benzothieno[2''3'':2'3']indeno[5'6':56]indeno[21-b][1]benzothiophene chloroform solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1589136: Experimental Crystal Structure Determination

2020

Related Article: Joshua E. Barker, Justin J. Dressler, Abel Cárdenas Valdivia, Ryohei Kishi, Eric T. Strand, Lev N. Zakharov, Samantha N. MacMillan, Carlos J. Gómez-García, Masayoshi Nakano, Juan Casado, Michael M. Haley|2019|J.Am.Chem.Soc.|142|1548|doi:10.1021/jacs.9b11898

Space GroupCrystallography816-bis[246-tri-isopropylphenyl][1]benzothieno[3''2'':2'3']indeno[5'6':56]indeno[12-b][1]benzothiophene acetonitrile solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

PEPhysical Sciences and Engineering
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