0000000001305747

AUTHOR

Jashobanta Sahoo

showing 4 related works from this author

Coordinatively Unsaturated Lanthanide(III) Helicates: Luminescence Sensors for Adenosine Monophosphate in Aqueous Media

2016

Coordinatively unsaturated double-stranded helicates [(H2 L)2 Eu2 (NO3 )2 (H2 O)4 ](NO3 )4 , [(H2 L)2 Tb2 (H2 O)6 ](NO3 )6 , and [(H2 L)2 Tb2 (H2 O)6 ]Cl6 (H2 L=butanedioicacid-1,4-bis[2-(2-pyridinylmethylene)hydrazide]) are easily obtained by self-assembly from the ligand and the corresponding lanthanide(III) salts. The complexes are characterized by X-ray crystallography showing the helical arrangement of the ligands. Co-ligands at the metal ions can be easily substituted by appropriate anions. A specific luminescence response of AMP in presence of ADP, ATP, and other anions is observed. Specificity is assigned to the perfect size match of AMP to bridge the two metal centers and to replac…

LanthanideCoordination sphereadenosine monophosphateStereochemistryMetal ions in aqueous solutionHydrazide010402 general chemistry01 natural sciencesCatalysisMetalchemistry.chemical_compoundluminescencelanthanidesta116sensingQuenching (fluorescence)ChemistryLigand010405 organic chemistryhelicatesGeneral ChemistryGeneral Medicine0104 chemical sciences3. Good healthCrystallographyvisual_artvisual_art.visual_art_mediumLuminescenceAngewandte Chemie International Edition
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CCDC 1453996: Experimental Crystal Structure Determination

2016

Related Article: Jashobanta Sahoo, Rajendran Arunachalam, Palani S. Subramanian, Eringathodi Suresh, Arto Valkonen, Kari Rissanen, Markus Albrecht|2016|Angew.Chem.,Int.Ed.|55|9625|doi:10.1002/anie.201604093

Space GroupCrystallographybis(mu-N'1-((pyridin-2-yl)methylene)-N'4-((pyridin-2-yl)methylene)succinohydrazide)-hexa-aqua-di-terbium(iii) hexachloride unknown solvate heptahydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1453997: Experimental Crystal Structure Determination

2016

Related Article: Jashobanta Sahoo, Rajendran Arunachalam, Palani S. Subramanian, Eringathodi Suresh, Arto Valkonen, Kari Rissanen, Markus Albrecht|2016|Angew.Chem.,Int.Ed.|55|9625|doi:10.1002/anie.201604093

Space GroupCrystallographybis(mu-N'1-((pyridin-2-yl)methylene)-N'4-((pyridin-2-yl)methylene)succinohydrazide)-bis(nitrato)-tetra-aqua-di-europium(iii) tetranitrate tetrahydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1458068: Experimental Crystal Structure Determination

2016

Related Article: Jashobanta Sahoo, Rajendran Arunachalam, Palani S. Subramanian, Eringathodi Suresh, Arto Valkonen, Kari Rissanen, Markus Albrecht|2016|Angew.Chem.,Int.Ed.|55|9625|doi:10.1002/anie.201604093

Space GroupCrystallographyCrystal SystemCrystal Structurebis(mu-(N'1-((pyridin-2-yl)methylene)-N'4-((pyridin-2-yl)methylene)succinohydrazide))-hexa-aqua-di-terbium hexanitrate hemihydrateCell ParametersExperimental 3D Coordinates
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