0000000001305794

AUTHOR

Ezequiel M. Vázquez-lópez

showing 5 related works from this author

Metallosupramolecular compounds based on Cu(ii)/oxalate/twisted NSSN ligands showing a new in situ S–C bond cleavage

2013

Four new complexes, [Cu2(C2O4) 2(SCS)]·3H2O (1), [Cu2(C 2O4)3(SCSH)2]·H2O (2), [Cu(C2O4)(SS)2]·3H2O (3) and [Cu(C2O4)(SS)]·6H2O (4) [where SCS = bis(4-pyridylthio)methane and SS = 4,4′-dipyridyldisulfide], have been synthesized by the reaction of the SS and SCS ligands with the corresponding copper(ii) oxalate salt. The different synthetic conditions allowed control of the preparation of a 3D open metal-organic framework in 1, a dinuclear zwitterionic molecular compound in 2 and one- and two-dimensional (1D and 2D) coordination polymers in 3 and 4, respectively. Compound 4 was also obtained by in situ transformation of the dithioether ligand (SCS) to the disulfide ligand (SS) under hydrothe…

BinodalLigandStereochemistrychemistry.chemical_elementGeneral ChemistryCrystal structureCondensed Matter PhysicsCopperOxalatechemistry.chemical_compoundCrystallographychemistryAntiferromagnetismMoleculeGeneral Materials ScienceBond cleavageCrystEngComm
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CCDC 919615: Experimental Crystal Structure Determination

2013

Related Article: Ana Belén Lago, Rosa Carballo, Oscar Fabelo, Nuria Fernández-Hermida, Francesc Lloret, Ezequiel M. Vázquez-López|2013|CrystEngComm|15|10550|doi:10.1039/C3CE41525B

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-((mu~2~-44'-Disulfanediyldipyridine)-(mu~2~-oxalato)-copper hexahydrate)
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CCDC 919613: Experimental Crystal Structure Determination

2013

Related Article: Ana Belén Lago, Rosa Carballo, Oscar Fabelo, Nuria Fernández-Hermida, Francesc Lloret, Ezequiel M. Vázquez-López|2013|CrystEngComm|15|10550|doi:10.1039/C3CE41525B

Space GroupCrystallographyCrystal System(mu2-oxalato)-bis(4-([(pyridin-4-ylsulfanyl)methyl]sulfanyl)pyridinium)-dioxalato-di-copper(ii) dihydrateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 919614: Experimental Crystal Structure Determination

2013

Related Article: Ana Belén Lago, Rosa Carballo, Oscar Fabelo, Nuria Fernández-Hermida, Francesc Lloret, Ezequiel M. Vázquez-López|2013|CrystEngComm|15|10550|doi:10.1039/C3CE41525B

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu2-oxalato)-tetrakis(44'-disulfanediyldipyridine)-di-copper hexahydrate]Experimental 3D Coordinates
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CCDC 919612: Experimental Crystal Structure Determination

2013

Related Article: Ana Belén Lago, Rosa Carballo, Oscar Fabelo, Nuria Fernández-Hermida, Francesc Lloret, Ezequiel M. Vázquez-López|2013|CrystEngComm|15|10550|doi:10.1039/C3CE41525B

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[(mu~4~-oxalato)-(mu~2~-oxalato)-(mu~2~-44'-(methanediyldisulfanediyl)dipyridine)-di-copper(ii)]Experimental 3D Coordinates
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