0000000001306122
AUTHOR
M.c. Gimenez
Heat-induced charge transfer in cobalt iron cyanide
The heating of Co(2+) ferricyanide above 801C induces an inner charge transfer from Co(2+) towards Fe(III) to form the mixed valence system Co(2+)Co(III) ferri- ferro-cyanide. This charge transfer takes place preserving the material framework and forming a solid solution of the initial and final species. The cell edge of the cubic cell (Fm-3m) of this solid solution follows a regular variation with
CCDC 203684: Experimental Crystal Structure Determination
Related Article: E.Coronado, M.C.Gimenez, C.J.Gomez-Garcia, F.M.Romero|2003|Polyhedron|22|3115|doi:10.1016/S0277-5387(03)00462-5