0000000001306157

AUTHOR

Roberto Puentes

Mononuclear and polynuclear complexes ligated by an iminodiacetic acid derivative: synthesis, structure, solution studies and magnetic properties

Two novel families of coordination polymers, [Ln(bzlida)(Hbzlida)]·H2O (Ln = La, Nd) and [Ln2(bzlida)3]·3H2O (Ln = Nd, Sm, Eu, Gd) were prepared by hydrothermal reaction of Ln2O3 with benzyliminodiacetic acid (H2bzlida). The conditions of synthesis, in particular the pH value, were selected on the basis of previous speciation studies reported in this work. The first type of complex consists of 1D chains built by a fully deprotonated ligand bridging two lanthanide ions and protonated Hbzlida(-) ligands connecting three cations. The second type is formed by [Ln2(bzlida)3] bimetallic units in which the ligand has a tridentate NOO coordination mode. This is expanded to a 2D network through carb…

research product

CCDC 1400954: Experimental Crystal Structure Determination

Related Article: Roberto Puentes, Julia Torres, Carlos Kremer, Joan Cano, Francesc Lloret, Davide Capucci, Alessia Bacchi|2016|Dalton Trans.|45|5356|doi:10.1039/C5DT05060J

research product

CCDC 1400958: Experimental Crystal Structure Determination

Related Article: Roberto Puentes, Julia Torres, Carlos Kremer, Joan Cano, Francesc Lloret, Davide Capucci, Alessia Bacchi|2016|Dalton Trans.|45|5356|doi:10.1039/C5DT05060J

research product

CCDC 1400956: Experimental Crystal Structure Determination

Related Article: Roberto Puentes, Julia Torres, Carlos Kremer, Joan Cano, Francesc Lloret, Davide Capucci, Alessia Bacchi|2016|Dalton Trans.|45|5356|doi:10.1039/C5DT05060J

research product

CCDC 1400955: Experimental Crystal Structure Determination

Related Article: Roberto Puentes, Julia Torres, Carlos Kremer, Joan Cano, Francesc Lloret, Davide Capucci, Alessia Bacchi|2016|Dalton Trans.|45|5356|doi:10.1039/C5DT05060J

research product

CCDC 1400953: Experimental Crystal Structure Determination

Related Article: Roberto Puentes, Julia Torres, Carlos Kremer, Joan Cano, Francesc Lloret, Davide Capucci, Alessia Bacchi|2016|Dalton Trans.|45|5356|doi:10.1039/C5DT05060J

research product

CCDC 1400957: Experimental Crystal Structure Determination

Related Article: Roberto Puentes, Julia Torres, Carlos Kremer, Joan Cano, Francesc Lloret, Davide Capucci, Alessia Bacchi|2016|Dalton Trans.|45|5356|doi:10.1039/C5DT05060J

research product

CCDC 1400952: Experimental Crystal Structure Determination

Related Article: Roberto Puentes, Julia Torres, Carlos Kremer, Joan Cano, Francesc Lloret, Davide Capucci, Alessia Bacchi|2016|Dalton Trans.|45|5356|doi:10.1039/C5DT05060J

research product