0000000001306273

AUTHOR

R. Broussier

showing 13 related works from this author

Chlorodicyclopentadienyloxoniobium(V) complexes revisited: The origin of the asymmetry in the 1H- and 13C-NMR spectra, X-ray crystal structures and a…

2000

Abstract 1H- and 13C-NMR spectra of chlorodicyclopentadienyloxoniobium(V) complex I and its four 1,1′-dialkyl substituted derivatives II–V have been recorded and assigned based on DQF 1H,1H-COSY and PFG 1H,13C-HMQC and HMBC experiments. Non-equivalences of all cyclopentadienyl protons and carbons in II–V (as reflected by their different 1H- and 13C-NMR chemical shifts) are explained by synchronous and out-of-phase rotations of the substituted cyclopentadienyl rings. A non-equivalence of the methyls in III (1,1′-di-isopropyl) is explained by a detailed inspection of the rotamers of the isopropyl groups. The X-ray structural data show that III and IV (1-methyl-1′-tert-butyl) crystallize in th…

ChemistryChemical shiftOrganic ChemistryAb initioSpace groupCrystal structureTriclinic crystal systemBiochemistryInorganic ChemistryCrystallographyCyclopentadienyl complexMaterials ChemistryPhysical and Theoretical ChemistryConformational isomerismMonoclinic crystal system
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CCDC 163669: Experimental Crystal Structure Determination

2002

Related Article: E.Andre-Bentabet, R.Broussier, R.Amardeil, J.-C.Hierso, P.Richard, D.Fasseur, B.Gautheron, P.Meunier|2002|J.Chem.Soc.,Dalton Trans.||2322|doi:10.1039/b108833p

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersTricarbonyl-(11'22'-tetrakis(diphenylphosphino)-44'-bis(t-butyl)ferrocene-PP'P'')-molybdenum toluene solvateExperimental 3D Coordinates
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CCDC 228540: Experimental Crystal Structure Determination

2004

Related Article: A.Fihri, J.-C.Hierso, V.V.Ivanov, B.Rebiere, R.Amardeil, R.Broussier, P.Meunier|2004|Inorg.Chim.Acta|357|3089|doi:10.1016/j.ica.2004.01.012

Space GroupCrystallographyCrystal SystemCrystal Structurebis(mu~2~-t-butylthiolato)-(mu~2~-11'-bis(bis(5-methyl-2-furyl)phosphino)ferrocene)-dicarbonyl-di-rhodiumCell ParametersExperimental 3D Coordinates
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CCDC 117663: Experimental Crystal Structure Determination

2000

Related Article: R.Broussier, E.Bentabet, P.Mellet, O.Blacque, P.Boyer, M.M.Kubicki, B.Gautheron|2000|J.Organomet.Chem.|598|365|doi:10.1016/S0022-328X(99)00736-6

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersrac-11'-bis(Diphenylphosphino)-33'-di-t-butylferroceneExperimental 3D Coordinates
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CCDC 142833: Experimental Crystal Structure Determination

2001

Related Article: R.Broussier, E.Bentabet, M.Laly, P.Richard, L.G.Kuz'mina, P.Serp, N.Wheatley, P.Kalck, B.Gautheron|2000|J.Organomet.Chem.|613|77|doi:10.1016/S0022-328X(00)00501-5

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersDichloro-(4-t-butyl-12-bis(diphenylphosphino)ferrocene-PP')-palladium(ii) dichloromethane solvateExperimental 3D Coordinates
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CCDC 163670: Experimental Crystal Structure Determination

2002

Related Article: E.Andre-Bentabet, R.Broussier, R.Amardeil, J.-C.Hierso, P.Richard, D.Fasseur, B.Gautheron, P.Meunier|2002|J.Chem.Soc.,Dalton Trans.||2322|doi:10.1039/b108833p

Space GroupCrystallography(eta^5^-Cyclopentadienyl)-carbonyl-(11'22'-tetrakis(diphenylphosphino)-44'-bis(t-butyl)ferrocene-PP')-manganese pentane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 141156: Experimental Crystal Structure Determination

2001

Related Article: E.Kolehmainen, K.Laihia, M.Nissinen, J.Linnanto, A.Perjessy, B.Gautheron, R.Broussier|2000|J.Organomet.Chem.|613|7|doi:10.1016/S0022-328X(00)00467-8

Space GroupCrystallographyChloro-bis(eta^5^-1-isopropylcyclopentadienyl)-oxo-niobium(v)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 117664: Experimental Crystal Structure Determination

2000

Related Article: R.Broussier, E.Bentabet, P.Mellet, O.Blacque, P.Boyer, M.M.Kubicki, B.Gautheron|2000|J.Organomet.Chem.|598|365|doi:10.1016/S0022-328X(99)00736-6

Space GroupCrystallographyCrystal SystemCrystal Structure12-bis(Diphenylphosphino)-4-t-butylferroceneCell ParametersExperimental 3D Coordinates
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CCDC 117662: Experimental Crystal Structure Determination

2000

Related Article: R.Broussier, E.Bentabet, P.Mellet, O.Blacque, P.Boyer, M.M.Kubicki, B.Gautheron|2000|J.Organomet.Chem.|598|365|doi:10.1016/S0022-328X(99)00736-6

Space GroupCrystallographyCrystal SystemCrystal Structuremeso-11'-bis(Diphenylphosphino)-33'-di-t-butylferroceneCell ParametersExperimental 3D Coordinates
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CCDC 141155: Experimental Crystal Structure Determination

2001

Related Article: E.Kolehmainen, K.Laihia, M.Nissinen, J.Linnanto, A.Perjessy, B.Gautheron, R.Broussier|2000|J.Organomet.Chem.|613|7|doi:10.1016/S0022-328X(00)00467-8

Space GroupCrystallographyCrystal SystemCrystal Structure(eta^5^-1-t-Butylcyclopentadienyl)-chloro-(eta^5^-1-methylcyclopentadienyl)-oxo-niobium(v)Cell ParametersExperimental 3D Coordinates
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CCDC 150996: Experimental Crystal Structure Determination

2002

Related Article: R.Broussier, E.Bentabet, R.Amardeil, P.Richard, P.Meunier, P.Kalck, B.Gautheron|2001|J.Organomet.Chem.|637|126|doi:10.1016/S0022-328X(01)00883-X

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters11'22'-tetrakis(Diphenylphosphino)-44'-bis(t-butyl)ferrocene toluene solvateExperimental 3D Coordinates
researchProduct

CCDC 117661: Experimental Crystal Structure Determination

2000

Related Article: R.Broussier, E.Bentabet, P.Mellet, O.Blacque, P.Boyer, M.M.Kubicki, B.Gautheron|2000|J.Organomet.Chem.|598|365|doi:10.1016/S0022-328X(99)00736-6

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters13-bis(Diphenylphosphino)ferroceneExperimental 3D Coordinates
researchProduct

CCDC 142834: Experimental Crystal Structure Determination

2001

Related Article: R.Broussier, E.Bentabet, M.Laly, P.Richard, L.G.Kuz'mina, P.Serp, N.Wheatley, P.Kalck, B.Gautheron|2000|J.Organomet.Chem.|613|77|doi:10.1016/S0022-328X(00)00501-5

Dichloro-(22'33'44'55'-octamethyl-1-diphenylphosphino-1'-(diphenylphosphine sulfide)ferrocene-PS)-palladium(ii) dichloromethane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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