0000000001306562
AUTHOR
Beatriz Rasines
Cadmium(ii) coordination polymers based on substituted malonic acid: synthesis, characterization and photoluminescence properties
Four novel complexes of cadmium(II) with alkyl/aryl-substituted malonate ligands of formulae {[Cd(Memal)(H2O)]6·0.5H2O}n (1), [Cd(Etmal)(H2O)]n (2), [Cd(Butmal)(H2O)]n (3) and [Cd(Bzmal)(H2O)]n (4), (Memal = methylmalonate, Etmal = ethylmalonate, Butmal = butylmalonate and Bzmal = benzylmalonate) have been prepared and characterized by single crystal X-ray analysis. Their luminescence, UV-Vis absorption properties and thermal behaviour were also investigated. Complex 1 is a three-dimensional compound where each metal centre is connected to four other ones leading to a sodalite network with the point symbol {42·64}. Each cadmium(II) ion in 1 is seven-coordinate with a water molecule and six …
CCDC 1545085: Experimental Crystal Structure Determination
Related Article: Mariadel Déniz, Jorge Pasán, Beatriz Rasines, Pablo Lorenzo-Luis, Fernando Lahoz, Corina Vera-Gonzales, Miguel Julve, Catalina Ruiz-Pérez|2017|Inorg.Chem.Front.|4|1384|doi:10.1039/C7QI00212B
CCDC 1545086: Experimental Crystal Structure Determination
Related Article: Mariadel Déniz, Jorge Pasán, Beatriz Rasines, Pablo Lorenzo-Luis, Fernando Lahoz, Corina Vera-Gonzales, Miguel Julve, Catalina Ruiz-Pérez|2017|Inorg.Chem.Front.|4|1384|doi:10.1039/C7QI00212B
CCDC 1545087: Experimental Crystal Structure Determination
Related Article: Mariadel Déniz, Jorge Pasán, Beatriz Rasines, Pablo Lorenzo-Luis, Fernando Lahoz, Corina Vera-Gonzales, Miguel Julve, Catalina Ruiz-Pérez|2017|Inorg.Chem.Front.|4|1384|doi:10.1039/C7QI00212B
CCDC 1545088: Experimental Crystal Structure Determination
Related Article: Mariadel Déniz, Jorge Pasán, Beatriz Rasines, Pablo Lorenzo-Luis, Fernando Lahoz, Corina Vera-Gonzales, Miguel Julve, Catalina Ruiz-Pérez|2017|Inorg.Chem.Front.|4|1384|doi:10.1039/C7QI00212B