0000000001306596
AUTHOR
P. J. Bereciartua
Isoreticular two-dimensional magnetic coordination polymers prepared through pre-synthetic ligand functionalization
Chemical functionalization is a powerful approach to tailor the physical and chemical properties of two-dimensional (2D) materials, increase their processability and stability, tune their functionalities and, even, create new 2D materials. This is typically achieved through post-synthetic functionalization by anchoring molecules on the surface of an exfoliated 2D crystal, but it inevitably alters the long-range structural order of the material. Here we present a pre-synthetic approach that allows the isolation of crystalline, robust and magnetic functionalized monolayers of coordination polymers. A series of five isostructural layered magnetic coordination polymers based on Fe(ii) centres a…
Defect-Free Chemical Functionalization of Magnetic Monolayers Based on Coordination Polymers
<p>Chemical functionalization has demonstrated to be a powerful approach to tailor the physical and chemical properties of two-dimensional (2D) materials, to increase their processability and</p> <p>stability, to add new functionalities and, even, to create new 2D materials. However, this post synthetic method – which involves the anchoring of molecules on the surface of an exfoliated 2D crystal – inevitably leads to defective materials, which lack long-range structural order. If defect-free functionalized monolayers are required, a radically new approach needs to be developed. Here we present a pre-synthetic method based on coordination chemistry that affords the isolatio…
CCDC 1849147: Experimental Crystal Structure Determination
Related Article: J. López-Cabrelles, S. Mañas-Valero, I. J. Vitóriza-Yrezábal, P. J. Bereciartua, J. A. Rodríguez-Velamazán, J. C. Waerenborgh, B. J. C. Vieira, D. Davidovikj, P. G. Steeneken, H. S. J. van der Zant, G. Mínguez Espallargas, E. Coronado|2018|Nature Chemistry|10|1001|doi:10.1038/s41557-018-0113-9
CCDC 1582347: Experimental Crystal Structure Determination
Related Article: J. López-Cabrelles, S. Mañas-Valero, I. J. Vitóriza-Yrezábal, P. J. Bereciartua, J. A. Rodríguez-Velamazán, J. C. Waerenborgh, B. J. C. Vieira, D. Davidovikj, P. G. Steeneken, H. S. J. van der Zant, G. Mínguez Espallargas, E. Coronado|2018|Nature Chemistry|10|1001|doi:10.1038/s41557-018-0113-9
CCDC 1582349: Experimental Crystal Structure Determination
Related Article: J. López-Cabrelles, S. Mañas-Valero, I. J. Vitóriza-Yrezábal, P. J. Bereciartua, J. A. Rodríguez-Velamazán, J. C. Waerenborgh, B. J. C. Vieira, D. Davidovikj, P. G. Steeneken, H. S. J. van der Zant, G. Mínguez Espallargas, E. Coronado|2018|Nature Chemistry|10|1001|doi:10.1038/s41557-018-0113-9
CCDC 1582350: Experimental Crystal Structure Determination
Related Article: J. López-Cabrelles, S. Mañas-Valero, I. J. Vitóriza-Yrezábal, P. J. Bereciartua, J. A. Rodríguez-Velamazán, J. C. Waerenborgh, B. J. C. Vieira, D. Davidovikj, P. G. Steeneken, H. S. J. van der Zant, G. Mínguez Espallargas, E. Coronado|2018|Nature Chemistry|10|1001|doi:10.1038/s41557-018-0113-9
CCDC 1582348: Experimental Crystal Structure Determination
Related Article: J. López-Cabrelles, S. Mañas-Valero, I. J. Vitóriza-Yrezábal, P. J. Bereciartua, J. A. Rodríguez-Velamazán, J. C. Waerenborgh, B. J. C. Vieira, D. Davidovikj, P. G. Steeneken, H. S. J. van der Zant, G. Mínguez Espallargas, E. Coronado|2018|Nature Chemistry|10|1001|doi:10.1038/s41557-018-0113-9