0000000001306623

AUTHOR

Qinchao Sun

showing 6 related works from this author

Structural, photophysical and magnetic properties of transition metal complexes based on the dipicolylamino-chloro-1,2,4,5-tetrazine ligand

2015

International audience; The ligand 3-chloro-6-dipicolylamino-1,2,4,5-tetrazine (Cl-TTZ-dipica) 1, prepared by the direct reaction between 3,6-dichloro-1,2,4,5-tetrazine and di(2-picolyl)-amine, afforded a series of four neutral transition metal complexes formulated as [Cl-TTZ-dipica-MCl2]2, with M = Zn(II), Cd(II), Mn(II) and Co(II), when reacted with the corresponding metal chlorides. The dinuclear structure of the isostructural complexes was disclosed by single crystal X-ray analysis, clearly indicating the formation of [MII–(μ-Cl)2MII] motifs and the involvement of the amino nitrogen atom in semi-coordination with the metal centers, thus leading to distorted octahedral coordination geome…

010405 organic chemistryChemistryLigandStereochemistrySubstituentSupramolecular chemistry010402 general chemistry01 natural sciences0104 chemical sciencesInorganic ChemistryMetalchemistry.chemical_compoundTetrazineCrystallographyTransition metalvisual_artIntramolecular forceddc:540visual_art.visual_art_medium[CHIM]Chemical Sciences[CHIM.COOR]Chemical Sciences/Coordination chemistryIsostructuralComputingMilieux_MISCELLANEOUSDALTON TRANSACTIONS
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CCDC 1045096: Experimental Crystal Structure Determination

2015

Related Article: Iuliia Nazarenko, Flavia Pop, Qinchao Sun, Andreas Hauser, Francesc Lloret, Miguel Julve, Abdelkrim El-Ghayoury, Narcis Avarvari|2015|Dalton Trans.|44|8855|doi:10.1039/C5DT00550G

Space GroupCrystallographyCrystal Systembis(mu-chloro)-dichloro-bis(6-chloro-NN-bis((pyridin-2-yl)methyl)-1245-tetrazin-3-amine)-di-manganese(ii)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1045094: Experimental Crystal Structure Determination

2015

Related Article: Iuliia Nazarenko, Flavia Pop, Qinchao Sun, Andreas Hauser, Francesc Lloret, Miguel Julve, Abdelkrim El-Ghayoury, Narcis Avarvari|2015|Dalton Trans.|44|8855|doi:10.1039/C5DT00550G

Space GroupCrystallographydichloro-(6-chloro-NN-bis((pyridin-2-yl)methyl)-1245-tetrazin-3-amine)-zinc(ii)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1045095: Experimental Crystal Structure Determination

2015

Related Article: Iuliia Nazarenko, Flavia Pop, Qinchao Sun, Andreas Hauser, Francesc Lloret, Miguel Julve, Abdelkrim El-Ghayoury, Narcis Avarvari|2015|Dalton Trans.|44|8855|doi:10.1039/C5DT00550G

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-chloro)-dichloro-bis(6-chloro-NN-bis(pyridin-2-ylmethyl)-1245-tetrazin-3-amine)-di-cadmium(ii)Experimental 3D Coordinates
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CCDC 1045093: Experimental Crystal Structure Determination

2015

Related Article: Iuliia Nazarenko, Flavia Pop, Qinchao Sun, Andreas Hauser, Francesc Lloret, Miguel Julve, Abdelkrim El-Ghayoury, Narcis Avarvari|2015|Dalton Trans.|44|8855|doi:10.1039/C5DT00550G

Space GroupCrystallography6-chloro-NN-bis(pyridin-2-ylmethyl)-1245-tetrazin-3-amineCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1045097: Experimental Crystal Structure Determination

2015

Related Article: Iuliia Nazarenko, Flavia Pop, Qinchao Sun, Andreas Hauser, Francesc Lloret, Miguel Julve, Abdelkrim El-Ghayoury, Narcis Avarvari|2015|Dalton Trans.|44|8855|doi:10.1039/C5DT00550G

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-chloro)-dichloro-bis(6-chloro-NN-bis((pyridin-2-yl)methyl)-1245-tetrazin-3-amine)-di-cobalt(ii)Experimental 3D Coordinates
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