0000000001306646
AUTHOR
L.e. Ochando
Coordination behavior of cinoxacine: Synthesis and crystal structure of tris (cinoxacinate) cobaltate(II) of sodium hexahydrate (HCx = 1-ethyl-4(1H) -oxo-(1,3) dioxolo-(4,5g) cinnoline-3-carboxylic acid)
The synthesis, crystal, and molecular structure of Co(Cx)3Na6H2O are reported. The Cobalt(II) compound crystallizes in the trigonal system, space group R 3 with Z = 6, in a cell of dimensions a= 18.688(7) (A), c= 20.142(6) A. Least-squares refinement of 1331 reflections [I≥3σ(I)] gave a final R = 0.088 for all observed reflections. The structure consists of anionic monomeric units of (Co(Cx)3−) and sodium cations. Three Cinoxacinate ions are chelated through Oceto and Ocarbox atoms. The Co(II) ion positioned on the third axis is bonded to six oxygen atoms in a slightly distorted octahedral environment.
CCDC 603140: Experimental Crystal Structure Determination
Related Article: A.M.Costero, M.Colera, P.Gavina, S.Gil, L.E.Ochando|2006|New J.Chem.|30|1263|doi:10.1039/b607100g
CCDC 140896: Experimental Crystal Structure Determination
Related Article: A.M.Costero, E.Monrabal, C.Andreu, R.Martinez-Manez, J.Soto, M.Padilla-Tosta, T.Pardo, L.E.Ochando, J.M.Amigo|2000|J.Chem.Soc.,Dalton Trans.||361|doi:10.1039/a906342k
CCDC 273729: Experimental Crystal Structure Determination
Related Article: A.M.Costero, M.J.Banuls, M.J.Aurell, L.E.Ochando, A.Domenech|2005|Tetrahedron|61|10309|doi:10.1016/j.tet.2005.08.010
CCDC 1441443: Experimental Crystal Structure Determination
Related Article: K. Chulvi, A. Costero, L.E. Ochando, P. Gaviña|2015|Acta Crystallogr.,Sect.E:Cryst.Commun.|71|o1069|doi:10.1107/S2056989015023646