0000000001306968
AUTHOR
María Esteve-rochina
Semiconductor Porous Hydrogen-Bonded Organic Frameworks Based on Tetrathiafulvalene Derivatives.
Herein, we report on the use of tetrathiavulvalene-tetrabenzoic acid, H4TTFTB, to engender semiconductivity in porous hydrogen-bonded organic frameworks (HOFs). By tuning the synthetic conditions, three different polymorphs have been obtained, denoted MUV-20a, MUV-20b, and MUV-21, all of them presenting open structures (22, 15, and 27%, respectively) and suitable TTF stacking for efficient orbital overlap. Whereas MUV-21 collapses during the activation process, MUV-20a and MUV-20b offer high stability evacuation, with a CO2 sorption capacity of 1.91 and 1.71 mmol g-1, respectively, at 10 °C and 6 bar. Interestingly, both MUV-20a and MUV-20b present a zwitterionic character with a positively…
CCDC 2095301: Experimental Crystal Structure Determination
Related Article: Javier López-Cabrelles, Eugenia Miguel-Casañ, María Esteve-Rochina, Eduardo Andres-Garcia, Iñigo J. Vitórica-Yrezábal, Joaquín Calbo, Guillermo Mínguez Espallargas|2022|Chemical Science|13|842|doi:10.1039/D1SC04779E