0000000001306972

AUTHOR

Mikhail S. Grigoriev

showing 2 related works from this author

Imidazoporphyrins as supramolecular tectons: synthesis and self-assembly of zinc 2-(4-pyridyl)-1H-imidazo[4,5-b]porphyrinate

2019

International audience; 5,10,15,20-Tetramesityl-2-(4-pyridyl)-1H-imidazo[4,5-b]porphyrin (PyPor) bearing a pyridine donor site connected to the tetrapyrrolic macrocycle by a rigid imidazole linker was prepared in high yield by the condensation of the corresponding 2,3-dioxochlorin and 4-formylpyridine in the presence of ammonium acetate. After the insertion of a metal ion capable of metal–ligand axial coordination, namely Zn(II), this compound afforded self-complementary porphyrin PyPorZn which was suitable for self-assembly. In the crystals, this complex exists as a zigzag coordination polymer formed through the axial coordination of the pyridine nitrogen atom to the zinc ion of the neighb…

ChemistryLigandCoordination polymer[CHIM.ORGA]Chemical Sciences/Organic chemistrySupramolecular chemistrychemistry.chemical_element02 engineering and technologyGeneral ChemistryZinc010402 general chemistry021001 nanoscience & nanotechnologyCondensed Matter Physics01 natural sciencesPorphyrin0104 chemical scienceschemistry.chemical_compoundCrystallographyMonomerPyridineImidazoleGeneral Materials Science[CHIM.COOR]Chemical Sciences/Coordination chemistry0210 nano-technology
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CCDC 1871295: Experimental Crystal Structure Determination

2019

Related Article: Inna A. Abdulaeva, Kirill P. Birin, Anna A. Sinelshchikova, Mikhail S. Grigoriev, Konstantin A. Lyssenko, Yulia G. Gorbunova, Aslan Yu. Tsivadze, Alla Bessmertnykh-Lemeune|2019|CrystEngComm|21|1488|doi:10.1039/C8CE01992D

Space GroupCrystallographycatena-[(5101520-Tetramesityl-2-(4-pyridyl)-1H-imidazo[45-b]porphyrinato)-zinc(ii) toluene solvate]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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