0000000001307146

AUTHOR

Antoine Tissot

showing 16 related works from this author

Very Long-Lived Photogenerated High-Spin Phase of a Multistable Spin-Crossover Molecular Material

2018

The spin-crossover compound [Fe(n-Bu-im)3(tren)](PF6)2 shows an unusual long relaxation time of 20 h after light-induced excited spin state trapping when irradiating at 80 K. This is more than 40 times longer than when irradiating at 10 K. Optical absorption spectroscopy, magnetometry, and X-ray diffraction using synchrotron radiation were used to characterize and explain the different relaxation behaviors of this compound after irradiation below and above 70 K. Rearrangement of the butyl chains of the ligands occurring during the relaxation after irradiation above 70 K is thought to be responsible for the unusually long relaxation time at this temperature.

Spin statesAbsorption spectroscopy010405 organic chemistryChemistryRelaxation (NMR)General Chemistry[CHIM.MATE]Chemical Sciences/Material chemistry[CHIM.INOR]Chemical Sciences/Inorganic chemistry010402 general chemistry01 natural sciencesBiochemistryMolecular physicsCatalysis0104 chemical sciencesColloid and Surface ChemistrySpin crossoverPhase (matter)Excited state[CHIM.COOR]Chemical Sciences/Coordination chemistryIrradiationSpin (physics)ComputingMilieux_MISCELLANEOUSJournal of the American Chemical Society
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Stimuli responsive hybrid magnets : tuning the photoinduced spin-crossover in Fe(III) complexes inserted into layered magnets

2013

The insertion of a [Fe(sal_2 trien)]^+ complex cation into a 2D oxalate network in the presence of different solvents results in a family of hybrid magnets with coexistence of magnetic ordering and photoinduced spin crossover (LIESST effect) in compounds [Fe^{III}(sal_2 trien)][Mn^{II}Cr^{III}(ox)_3]·CHCl_3 (1·CHCl_{3}) [Fe^{III}(sal_{2} trien)][Mn^{II}Cr^{III}(ox)_{3}]·CHBr_{3} (1·CHBr_{3}) and [Fe^{III}(sal_{2} trien)][Mn^{II}Cr^{III}(ox)_{3}]·CH_{2}Br_{2} (1·CH_{2}Br_{2}). The three compounds crystallize in a 2D honeycomb anionic layer formed by Mn^{II} and Cr^{III} ions linked through oxalate ligands and a layer of [Fe(sal_{2} trien)]^{+} complexes and solvent molecules (CHCl_{3} CHBr_{…

MagnetismInorganic chemistry010402 general chemistry01 natural sciencesBiochemistryCatalysisOxalateLIESSTchemistry.chemical_compoundColloid and Surface ChemistrySpin crossoverFe(III)Mössbauer spectroscopyOrganometallic CompoundsMoleculeMolecular Structure010405 organic chemistryChemistryRelaxation (NMR)Complex cationMagnetismHybrid magnetsGeneral ChemistryOxalate network[CHIM.MATE]Chemical Sciences/Material chemistryPhotochemical Processes0104 chemical sciencesCrystallographyMagnetic FieldsFerromagnetismddc:540Solvents
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CCDC 929206: Experimental Crystal Structure Determination

2014

Related Article: Miguel Clemente-León, Eugenio Coronado, Maurici López-Jordà, João C. Waerenborgh, Cédric Desplanches, Hongfeng Wang, Jean-François Létard, Andreas Hauser , and Antoine Tissot|2013|J.Am.Chem.Soc.|135|8655|doi:10.1021/ja402674x

Space GroupCrystallographyCrystal Systemcatena-(bis((22'-(25811-Tetra-azadodeca-111-diene-112-diyl)diphenolato)-iron) hexakis(mu~2~-oxalato)-tetra-chromium chloroform solvate)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 929201: Experimental Crystal Structure Determination

2014

Related Article: Miguel Clemente-León, Eugenio Coronado, Maurici López-Jordà, João C. Waerenborgh, Cédric Desplanches, Hongfeng Wang, Jean-François Létard, Andreas Hauser , and Antoine Tissot|2013|J.Am.Chem.Soc.|135|8655|doi:10.1021/ja402674x

Space GroupCrystallographyCrystal Systemcatena-(bis((22'-(25811-Tetra-azadodeca-111-diene-112-diyl)diphenolato)-iron(iii)) hexakis(mu2-oxalato)-di-chromium(iii)-di-manganese(ii) dibromomethane solvate)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 929203: Experimental Crystal Structure Determination

2014

Related Article: Miguel Clemente-León, Eugenio Coronado, Maurici López-Jordà, João C. Waerenborgh, Cédric Desplanches, Hongfeng Wang, Jean-François Létard, Andreas Hauser , and Antoine Tissot|2013|J.Am.Chem.Soc.|135|8655|doi:10.1021/ja402674x

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(bis((22'-(25811-Tetra-azadodeca-111-diene-112-diyl)diphenolato)-iron(iii)) hexakis(mu2-oxalato)-di-chromium(iii)-di-manganese(ii) bromoform solvate)Experimental 3D Coordinates
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CCDC 929204: Experimental Crystal Structure Determination

2014

Related Article: Miguel Clemente-León, Eugenio Coronado, Maurici López-Jordà, João C. Waerenborgh, Cédric Desplanches, Hongfeng Wang, Jean-François Létard, Andreas Hauser , and Antoine Tissot|2013|J.Am.Chem.Soc.|135|8655|doi:10.1021/ja402674x

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(bis((22'-(25811-Tetra-azadodeca-111-diene-112-diyl)diphenolato)-iron) hexakis(mu~2~-oxalato)-tetra-chromium bromoform solvate)Experimental 3D Coordinates
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CCDC 1848631: Experimental Crystal Structure Determination

2018

Related Article: Teresa Delgado, Antoine Tissot, Laure Guénée, Andreas Hauser, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, José Antonio Real, Sébastien Pillet, El-Eulmi Bendeif, Céline Besnard|2018|J.Am.Chem.Soc.|140|12870|doi:10.1021/jacs.8b06042

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(NNN-tris(2-(((1-butyl-1H-imidazol-2-yl)methylidene)amino)ethyl)amine)-iron(ii) bis(hexafluorophosphate)Experimental 3D Coordinates
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CCDC 929205: Experimental Crystal Structure Determination

2014

Related Article: Miguel Clemente-León, Eugenio Coronado, Maurici López-Jordà, João C. Waerenborgh, Cédric Desplanches, Hongfeng Wang, Jean-François Létard, Andreas Hauser , and Antoine Tissot|2013|J.Am.Chem.Soc.|135|8655|doi:10.1021/ja402674x

Space GroupCrystallographyCrystal Systemcatena-(bis((22'-(25811-Tetra-azadodeca-111-diene-112-diyl)diphenolato)-iron) hexakis(mu~2~-oxalato)-tetra-chromium chloroform solvate)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1848628: Experimental Crystal Structure Determination

2018

Related Article: Teresa Delgado, Antoine Tissot, Laure Guénée, Andreas Hauser, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, José Antonio Real, Sébastien Pillet, El-Eulmi Bendeif, Céline Besnard|2018|J.Am.Chem.Soc.|140|12870|doi:10.1021/jacs.8b06042

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(NNN-tris(2-(((1-butyl-1H-imidazol-2-yl)methylidene)amino)ethyl)amine)-iron(ii) bis(hexafluorophosphate)Experimental 3D Coordinates
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CCDC 1857201: Experimental Crystal Structure Determination

2018

Related Article: Teresa Delgado, Antoine Tissot, Laure Guénée, Andreas Hauser, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, José Antonio Real, Sébastien Pillet, El-Eulmi Bendeif, Céline Besnard|2018|J.Am.Chem.Soc.|140|12870|doi:10.1021/jacs.8b06042

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(NNN-tris(2-(((1-butyl-1H-imidazol-2-yl)methylidene)amino)ethyl)amine)-iron(ii) bis(hexafluorophosphate)Experimental 3D Coordinates
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CCDC 929202: Experimental Crystal Structure Determination

2014

Related Article: Miguel Clemente-León, Eugenio Coronado, Maurici López-Jordà, João C. Waerenborgh, Cédric Desplanches, Hongfeng Wang, Jean-François Létard, Andreas Hauser , and Antoine Tissot|2013|J.Am.Chem.Soc.|135|8655|doi:10.1021/ja402674x

Space GroupCrystallographycatena-(bis((22'-(25811-Tetra-azadodeca-111-diene-112-diyl)diphenolato)-iron) hexakis(mu~2~-oxalato)-tetra-chromium dibromomethane solvate)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 929207: Experimental Crystal Structure Determination

2014

Related Article: Miguel Clemente-León, Eugenio Coronado, Maurici López-Jordà, João C. Waerenborgh, Cédric Desplanches, Hongfeng Wang, Jean-François Létard, Andreas Hauser , and Antoine Tissot|2013|J.Am.Chem.Soc.|135|8655|doi:10.1021/ja402674x

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(bis((22'-(25811-Tetraazadodeca-111-diene-112-diyl)diphenolato)-iron) hexakis(mu~2~-oxalato)-tetra-chromium dichloromethane solvate)Experimental 3D Coordinates
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CCDC 1848626: Experimental Crystal Structure Determination

2018

Related Article: Teresa Delgado, Antoine Tissot, Laure Guénée, Andreas Hauser, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, José Antonio Real, Sébastien Pillet, El-Eulmi Bendeif, Céline Besnard|2018|J.Am.Chem.Soc.|140|12870|doi:10.1021/jacs.8b06042

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(NNN-tris(2-(((1-butyl-1H-imidazol-2-yl)methylidene)amino)ethyl)amine)-iron(ii) bis(hexafluorophosphate)Experimental 3D Coordinates
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CCDC 929208: Experimental Crystal Structure Determination

2014

Related Article: Miguel Clemente-León, Eugenio Coronado, Maurici López-Jordà, João C. Waerenborgh, Cédric Desplanches, Hongfeng Wang, Jean-François Létard, Andreas Hauser , and Antoine Tissot|2013|J.Am.Chem.Soc.|135|8655|doi:10.1021/ja402674x

Space GroupCrystallographycatena-(bis((22'-(25811-Tetra-azadodeca-111-diene-112-diyl)diphenolato)-gallium) hexakis(mu2-oxalato)-tetra-chromium dichloromethane solvate)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1848629: Experimental Crystal Structure Determination

2018

Related Article: Teresa Delgado, Antoine Tissot, Laure Guénée, Andreas Hauser, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, José Antonio Real, Sébastien Pillet, El-Eulmi Bendeif, Céline Besnard|2018|J.Am.Chem.Soc.|140|12870|doi:10.1021/jacs.8b06042

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(NNN-tris(2-(((1-butyl-1H-imidazol-2-yl)methylidene)amino)ethyl)amine)-iron(ii) bis(hexafluorophosphate)Experimental 3D Coordinates
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CCDC 1848627: Experimental Crystal Structure Determination

2018

Related Article: Teresa Delgado, Antoine Tissot, Laure Guénée, Andreas Hauser, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, José Antonio Real, Sébastien Pillet, El-Eulmi Bendeif, Céline Besnard|2018|J.Am.Chem.Soc.|140|12870|doi:10.1021/jacs.8b06042

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(NNN-tris(2-(((1-butyl-1H-imidazol-2-yl)methylidene)amino)ethyl)amine)-iron(ii) bis(hexafluorophosphate)Experimental 3D Coordinates
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