Author: Fabio Montisci

0000000001307166

AUTHOR

Fabio Montisci

showing 3 related works from this author

Role of the Open-Shell Character on the Pressure-Induced Conductivity of an Organic Donor-Acceptor Radical Dyad

2018

Single‐component conductors based on neutral organic radicals have received a lot of attention due to the possibility that the unpaired electron can serve as a charge carrier without the need of a previous doping process. Although most of these systems are based on delocalized planar radicals, we present here a nonplanar and spin localized radical based on a tetrathiafulvalene (TTF) moiety, linked to a perchlorotriphenylmethyl (PTM) radical by a conjugated bridge, which exhibits a semiconducting behavior upon application of high pressure. The synthesis, electronic properties, and crystal structure of this neutral radical TTF‐Ph‐PTM derivative (1) are reported and implications of its crystal…

010405 organic chemistryChemistryRadicalOrganic ChemistryGeneral ChemistryOrganic radical010402 general chemistry01 natural sciencesCatalysisDonor-acceptor3. Good health0104 chemical sciencesSingle-component conductorDelocalized electronchemistry.chemical_compoundCrystallographyUnpaired electronTetrathiafulvaleneCharge carrierIsostructuralElectronic band structureOpen shellPolychlorotriphenylmethylTetrathiafulvaleneChemistry - A European Journal

researchProduct

CCDC 1817871: Experimental Crystal Structure Determination

2018

Related Article: Manuel Souto, Maria Chiara Gullo, HengBo Cui, Nicola Casati, Fabio Montisci, Harald O. Jeschke, Roser Valentí, Imma Ratera, Concepció Rovira, Jaume Veciana|2018|Chem.-Eur.J.|24|5500|doi:10.1002/chem.201800881

Space GroupCrystallography4-[4-(2-{4-[bis(pentachlorophenyl)methyl]-2356-tetrachlorophenyl}ethenyl)phenyl]-2-(2H-13-dithiol-2-ylidene)-2H-13-dithioleCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1817872: Experimental Crystal Structure Determination

2018

Related Article: Manuel Souto, Maria Chiara Gullo, HengBo Cui, Nicola Casati, Fabio Montisci, Harald O. Jeschke, Roser Valentí, Imma Ratera, Concepció Rovira, Jaume Veciana|2018|Chem.-Eur.J.|24|5500|doi:10.1002/chem.201800881

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters4-[4-(2-{4-[bis(pentachlorophenyl)methyl]-2356-tetrachlorophenyl}ethenyl)phenyl]-2-(2H-13-dithiol-2-ylidene)-2H-13-dithiole radicalExperimental 3D Coordinates

researchProduct

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