0000000001307333
AUTHOR
Esther Delgado
Unprecedented layered coordination polymers of dithiolene group 10 metals: Magnetic and electrical properties
One-pot reactions between Ni(ii), Pd(ii) or Pt(ii) salts and 3,6-dichloro-1,2-benzenedithiol (HSC6H2Cl2SH) in KOH medium under argon lead to a series of bis-dithiolene coordination polymers. X-ray analysis shows the presence of a common square planar complex [M(SC6H2Cl2S)2]2- linked to potassium cations forming either a two-dimensional coordination polymer network for {[K2(μ-H2O)2(μ-thf)(thf)2][M(SC6H2Cl2S)2]}n [M = Ni (1) and Pd (2)] or a one-dimensional coordination polymer for {[K2(μ-H2O)2(thf)6][Pt(SC6H2Cl2S)2]}n (3). In 3 the coordination environment of the potassium ions may slightly change leading to the two-dimensional coordination polymer {[K2(μ-H2O)(μ-thf)2][Pt(SC6H2Cl2S)2]}n (4) …
Electrical Bistability around Room Temperature in an Unprecedented One-Dimensional Coordination Magnetic Polymer
The synthesis, crystal structure, and physical properties of an unprecedented one-dimensional (1D) coordination polymer containing [Fe2(S2C6H2Cl2)4](2-) entities bridged by dicationic [K2(μ-H2O)2(THF)4](2+) units are described. The magnetic properties show that the title compound presents pairwise Fe-Fe antiferromagnetic interactions that can be well reproduced with a S = 1/2 dimer model with an exchange coupling, J = -23 cm(-1). The electrical conductivity measurements show that the title compound is a semiconductor with an activation energy of about 290 meV and two different transitions, both with large hysteresis of about 60 and 30 K at 260-320 K and 350-380 K, respectively. These two tr…
Group 10 Metal Benzene-1,2-dithiolate Derivatives in the Synthesis of Coordination Polymers Containing Potassium Countercations
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.7b01775
Coordination polymers based on diiron tetrakis(dithiolato) bridged by alkali metals, electrical bistability around room temperature, and strong antiferromagnetic coupling.
Coordination polymer chains have been formed by the direct reaction between HSC6H2Cl2SH and FeCl3·6H2O in the presence of an aqueous solution of the corresponding alkali-metal hydroxide (M = Li, Na, and K) or carbonate (M = Rb and Cs). The structures consist of dimeric [Fe2(SC6H2Cl2S)4](2-) entities bridged by [M2(THF)4] [M = K (1), Rb (2), and Cs (3); THF = tetrahydrofuran] or {[Na2(μ-H2O)2(THF)2] (5 and 5') units. The smaller size of the lithium atom yields an anion/cation ion-pair molecule, [Li(THF)4]2[Fe2(SC6H2Cl2S)4] (4), in which the dianionic moieties are held together by Cl···Cl interactions. Electrical characterization of these compounds shows a general semiconductor behavior in wh…
Comparative studies of oxidation processes on Group 10 Metals Dithiolene Derivatives in the formation of coordination polymers
This document is the Accepted Manuscript Version of a Published Work that appeared in final form in "Crystal Growth and Design", copyright © 2018 American Chemical Society after peer review and techical editing by publisher. To access the final and published work see "Comparative Studies of Oxidation Processes on Group 10 Metals Dithiolene Derivatives in the Formation of Coordination Polymers Oscar Castillo, Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Pilar Herrasti, Avelino Martín, and Félix Zamora Crystal Growth & Design 2018 18 (4), 2486-2494
CCDC 1583018: Experimental Crystal Structure Determination
Related Article: Oscar Castillo, Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Pilar Herrasti, Avelino Martín, Félix Zamora|2018|Cryst.Growth Des.|18|2486|doi:10.1021/acs.cgd.8b00103
CCDC 1054832: Experimental Crystal Structure Determination
Related Article: Samia Benmansour , Esther Delgado , Carlos J. Gómez-García , Diego Hernández , Elisa Hernández , Avelino Martin , Josefina Perles , and Félix Zamora|2015|Inorg.Chem.|54|2243|doi:10.1021/ic502789v
CCDC 1582338: Experimental Crystal Structure Determination
Related Article: Oscar Castillo, Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Pilar Herrasti, Avelino Martín, Félix Zamora|2018|Cryst.Growth Des.|18|2486|doi:10.1021/acs.cgd.8b00103
CCDC 1054830: Experimental Crystal Structure Determination
Related Article: Samia Benmansour , Esther Delgado , Carlos J. Gómez-García , Diego Hernández , Elisa Hernández , Avelino Martin , Josefina Perles , and Félix Zamora|2015|Inorg.Chem.|54|2243|doi:10.1021/ic502789v
CCDC 1450247: Experimental Crystal Structure Determination
Related Article: Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Avelino Martín, Félix Zamora|2016|Dalton Trans.|45|6696|doi:10.1039/C6DT00464D
CCDC 1583017: Experimental Crystal Structure Determination
Related Article: Oscar Castillo, Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Pilar Herrasti, Avelino Martín, Félix Zamora|2018|Cryst.Growth Des.|18|2486|doi:10.1021/acs.cgd.8b00103
CCDC 1054827: Experimental Crystal Structure Determination
Related Article: Samia Benmansour , Esther Delgado , Carlos J. Gómez-García , Diego Hernández , Elisa Hernández , Avelino Martin , Josefina Perles , and Félix Zamora|2015|Inorg.Chem.|54|2243|doi:10.1021/ic502789v
CCDC 1551942: Experimental Crystal Structure Determination
Related Article: Oscar Castillo, Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Avelino Martín, José I. Martínez, and Félix Zamora|2017|Inorg.Chem.|56|11810|doi:10.1021/acs.inorgchem.7b01775
CCDC 1583019: Experimental Crystal Structure Determination
Related Article: Oscar Castillo, Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Pilar Herrasti, Avelino Martín, Félix Zamora|2018|Cryst.Growth Des.|18|2486|doi:10.1021/acs.cgd.8b00103
CCDC 1551944: Experimental Crystal Structure Determination
Related Article: Oscar Castillo, Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Avelino Martín, José I. Martínez, and Félix Zamora|2017|Inorg.Chem.|56|11810|doi:10.1021/acs.inorgchem.7b01775
CCDC 1054831: Experimental Crystal Structure Determination
Related Article: Samia Benmansour , Esther Delgado , Carlos J. Gómez-García , Diego Hernández , Elisa Hernández , Avelino Martin , Josefina Perles , and Félix Zamora|2015|Inorg.Chem.|54|2243|doi:10.1021/ic502789v
CCDC 1450248: Experimental Crystal Structure Determination
Related Article: Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Avelino Martín, Félix Zamora|2016|Dalton Trans.|45|6696|doi:10.1039/C6DT00464D
CCDC 1054829: Experimental Crystal Structure Determination
Related Article: Samia Benmansour , Esther Delgado , Carlos J. Gómez-García , Diego Hernández , Elisa Hernández , Avelino Martin , Josefina Perles , and Félix Zamora|2015|Inorg.Chem.|54|2243|doi:10.1021/ic502789v
CCDC 1551943: Experimental Crystal Structure Determination
Related Article: Oscar Castillo, Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Avelino Martín, José I. Martínez, and Félix Zamora|2017|Inorg.Chem.|56|11810|doi:10.1021/acs.inorgchem.7b01775
CCDC 1583016: Experimental Crystal Structure Determination
Related Article: Oscar Castillo, Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Pilar Herrasti, Avelino Martín, Félix Zamora|2018|Cryst.Growth Des.|18|2486|doi:10.1021/acs.cgd.8b00103
CCDC 1450246: Experimental Crystal Structure Determination
Related Article: Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Avelino Martín, Félix Zamora|2016|Dalton Trans.|45|6696|doi:10.1039/C6DT00464D
CCDC 888484: Experimental Crystal Structure Determination
Related Article: Pilar Amo-Ochoa, Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Avelino Martin, and Félix Zamora|2013|Inorg.Chem.|52|5943|doi:10.1021/ic400158q
CCDC 1450245: Experimental Crystal Structure Determination
Related Article: Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Avelino Martín, Félix Zamora|2016|Dalton Trans.|45|6696|doi:10.1039/C6DT00464D
CCDC 1582337: Experimental Crystal Structure Determination
Related Article: Oscar Castillo, Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Pilar Herrasti, Avelino Martín, Félix Zamora|2018|Cryst.Growth Des.|18|2486|doi:10.1021/acs.cgd.8b00103
CCDC 1054828: Experimental Crystal Structure Determination
Related Article: Samia Benmansour , Esther Delgado , Carlos J. Gómez-García , Diego Hernández , Elisa Hernández , Avelino Martin , Josefina Perles , and Félix Zamora|2015|Inorg.Chem.|54|2243|doi:10.1021/ic502789v