0000000001307507

AUTHOR

Mathilde Rigoulet

showing 5 related works from this author

C−C Cross-Couplings from a Cyclometalated Au(III) C∧ N Complex: Mechanistic Insights and Synthetic Developments

2021

Abstract In recent years, the reactivity of gold complexes was shown to extend well beyond π‐activation and to hold promises to achieve selective cross‐couplings in several C−C and C−E (E=heteroatom) bond forming reactions. Here, with the aim of exploiting new organometallic species for cross‐coupling reactions, we report on the Au(III)‐mediated C(sp2)−C(sp) occurring upon reaction of the cyclometalated complex [Au(CCH2N)Cl2] (1, CCH2N=2‐benzylpyridine) with AgPhCC. The reaction progress has been monitored by NMR spectroscopy, demonstrating the involvement of a number of key intermediates, whose structures have been unambiguously ascertained through 1D and 2D NMR analyses (1H, 13C, 1H‐1H CO…

Coordination sphereHeteroatom010402 general chemistry01 natural sciencesCatalysisReductive eliminationNMR spectroscopyNucleophilecross-couplingReactivity (chemistry)Full Paper010405 organic chemistryChemistry[CHIM.ORGA]Chemical Sciences/Organic chemistryOrganic Chemistryreductive eliminationGeneral ChemistryNuclear magnetic resonance spectroscopy[CHIM.CATA]Chemical Sciences/CatalysisFull PapersTransition state0104 chemical sciencesgold cyclometalated complexesCrystallographyZincSettore CHIM/03 - Chimica Generale E InorganicaGoldTwo-dimensional nuclear magnetic resonance spectroscopyorganometallics
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CCDC 2082255: Experimental Crystal Structure Determination

2021

Related Article: Riccardo Bonsignore, Sophie R. Thomas, Mathilde Rigoulet, Christian Jandl, Alexander P��thig, Didier Bourissou, Giampaolo Barone, Angela Casini|2021|Chem.-Eur.J.|27|14322|doi:10.1002/chem.202102668

Space GroupCrystallographychloro-(2-(2-pyridylmethyl)phenyl)-(2-phenylethynyl)-goldCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2082254: Experimental Crystal Structure Determination

2021

Related Article: Riccardo Bonsignore, Sophie R. Thomas, Mathilde Rigoulet, Christian Jandl, Alexander Pöthig, Didier Bourissou, Giampaolo Barone, Angela Casini|2021|Chem.-Eur.J.|27|14322|doi:10.1002/chem.202102668

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(6-benzylidene-611-dihydropyrido[12-b]isoquinolin-5-ium)-chloro-gold chloro-(6-phenyl-12H-pyrido[21-b][3]benzazepin-5-ium)-gold(i) chloroform solvateExperimental 3D Coordinates
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CCDC 2082253: Experimental Crystal Structure Determination

2021

Related Article: Riccardo Bonsignore, Sophie R. Thomas, Mathilde Rigoulet, Christian Jandl, Alexander Pöthig, Didier Bourissou, Giampaolo Barone, Angela Casini|2021|Chem.-Eur.J.|27|14322|doi:10.1002/chem.202102668

Space GroupCrystallographyCrystal Systemchloro-(2-(2-pyridylmethyl)phenyl)-(2-phenylethynyl)-gold(iii)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2096758: Experimental Crystal Structure Determination

2021

Related Article: Riccardo Bonsignore, Sophie R. Thomas, Mathilde Rigoulet, Christian Jandl, Alexander Pöthig, Didier Bourissou, Giampaolo Barone, Angela Casini|2021|Chem.-Eur.J.|27|14322|doi:10.1002/chem.202102668

Space GroupCrystallographyCrystal System{2-[(pyridin-2-yl)methyl]phenyl}-bis(thiophen-2-yl)-gold(iii)Crystal StructureCell ParametersExperimental 3D Coordinates
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