0000000001307619

AUTHOR

Jessica N. Boynton

showing 10 related works from this author

Effects of Remote Ligand Substituents on the Structures, Spectroscopic, and Magnetic Properties of Two-Coordinate Transition-Metal Thiolate Complexes

2018

The first-row transition-metal(II) dithiolates M(SAriPr4)2 [AriPr4 = C6H3-2,6-(C6H3-2,6-iPr2)2; M = Cr (1), Mn (3), Fe (4), Co (5), Ni (6), and Zn (7)] and Cr(SArMe6)2 [2; ArMe6 = C6H3-2,6-(C6H2-2,4,6-Me3)2] and the ligand-transfer reagent (NaSAriPr4)2 (8) are described. In contrast to their M(SAriPr6)2 (M = Cr, Mn, Fe, Co, Ni, and Zn; AriPr6 = C6H3-2,6-(C6H2-2,4,6-iPr3)2) congeners, which differ from 1 and 3-6 in having p-isopropyl groups on the flanking aryl rings of the terphenyl substituents, compounds 1 and 4-6 display highly bent coordination geometries with S-M-S angles of 109.802(2)° (1), 120.2828(3)° (4), 91.730(3)° (5), and 92.68(2)° (6) as well as relatively close metal-flanking …

010405 organic chemistryLigandligandsArylkompleksiyhdisteetligandit010402 general chemistryRing (chemistry)01 natural sciencesElectron spectroscopy0104 chemical sciencesInorganic ChemistryMetalchemistry.chemical_compoundCrystallographychemistryTransition metalCovalent bondvisual_artTerphenylvisual_art.visual_art_mediumcoordination complexesPhysical and Theoretical Chemistryta116
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Counterintuitive Mechanisms of the Addition of Hydrogen and Simple Olefins to Heavy Group 13 Alkene Analogues

2013

The mechanism of the reaction of olefins and hydrogen with dimetallenes ArMMAr (Ar = aromatic group; M = Al or Ga) was studied by density functional theory calculations and experimental methods. The digallenes, for which the most experimental data are available, are extensively dissociated to gallanediyl monomers, :GaAr, in hydrocarbon solution, but the calculations and experimental data showed also that they react with simple olefins, such as ethylene, as intact ArGaGaAr dimers via stepwise [2 + 2 + 2] cycloadditions due to their considerably lower activation barriers vis-à-vis the gallanediyl monomers, :GaAr. This pathway was preferred over the [2 + 2] cycloaddition of olefin to monomeric…

EthyleneStereochemistryGalliumAlkenesBiochemistryMedicinal chemistryCatalysisPropenechemistry.chemical_compoundColloid and Surface ChemistryOrganometallic CompoundsSinglet stateta116chemistry.chemical_classificationOlefin fiberDiradicalChemistryAlkeneGeneral ChemistryCycloadditionCyclizationYield (chemistry)Quantum TheoryCyclobutanesAluminumHydrogenJournal of the American Chemical Society
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CCDC 1555899: Experimental Crystal Structure Determination

2018

Related Article: Jade Pratt, Aimee M. Bryan, Michelle Faust, Jessica N. Boynton, Petra Vasko, Brian D. Rekken, Akseli Mansikkamäki, James C. Fettinger, Heikki M. Tuononen, Philip P. Power|2018|Inorg.Chem.|57|6491|doi:10.1021/acs.inorgchem.8b00551

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis[12163236-tetrakis(propan-2-yl)[1121:2331-terphenyl]-22-thiolato]-chromium(ii) toluene solvateExperimental 3D Coordinates
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CCDC 1828738: Experimental Crystal Structure Determination

2018

Related Article: Jade Pratt, Aimee M. Bryan, Michelle Faust, Jessica N. Boynton, Petra Vasko, Brian D. Rekken, Akseli Mansikkamäki, James C. Fettinger, Heikki M. Tuononen, Philip P. Power|2018|Inorg.Chem.|57|6491|doi:10.1021/acs.inorgchem.8b00551

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-12163236-tetrakis(propan-2-yl)[1121:2331-terphenyl]-22-thiolato)-di-sodium hexane solvateExperimental 3D Coordinates
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CCDC 1555900: Experimental Crystal Structure Determination

2018

Related Article: Jade Pratt, Aimee M. Bryan, Michelle Faust, Jessica N. Boynton, Petra Vasko, Brian D. Rekken, Akseli Mansikkamäki, James C. Fettinger, Heikki M. Tuononen, Philip P. Power|2018|Inorg.Chem.|57|6491|doi:10.1021/acs.inorgchem.8b00551

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis[121416323436-hexamethyl[1121:2331-terphenyl]-22-thiolato]-chromium(ii) unknown solvateExperimental 3D Coordinates
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CCDC 1555898: Experimental Crystal Structure Determination

2018

Related Article: Jade Pratt, Aimee M. Bryan, Michelle Faust, Jessica N. Boynton, Petra Vasko, Brian D. Rekken, Akseli Mansikkamäki, James C. Fettinger, Heikki M. Tuononen, Philip P. Power|2018|Inorg.Chem.|57|6491|doi:10.1021/acs.inorgchem.8b00551

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis[12163236-tetrakis(propan-2-yl)[1121:2331-terphenyl]-22-thiolato]-cobalt(ii)Experimental 3D Coordinates
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CCDC 1555903: Experimental Crystal Structure Determination

2018

Related Article: Jade Pratt, Aimee M. Bryan, Michelle Faust, Jessica N. Boynton, Petra Vasko, Brian D. Rekken, Akseli Mansikkamäki, James C. Fettinger, Heikki M. Tuononen, Philip P. Power|2018|Inorg.Chem.|57|6491|doi:10.1021/acs.inorgchem.8b00551

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis[12163236-tetrakis(propan-2-yl)[1121:2331-terphenyl]-22-thiolato]-manganese(ii)Experimental 3D Coordinates
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CCDC 1555901: Experimental Crystal Structure Determination

2018

Related Article: Jade Pratt, Aimee M. Bryan, Michelle Faust, Jessica N. Boynton, Petra Vasko, Brian D. Rekken, Akseli Mansikkamäki, James C. Fettinger, Heikki M. Tuononen, Philip P. Power|2018|Inorg.Chem.|57|6491|doi:10.1021/acs.inorgchem.8b00551

Space GroupCrystallographyCrystal SystemCrystal Structurebis[12163236-tetrakis(propan-2-yl)[1121:2331-terphenyl]-22-thiolato]-zinc(ii)Cell ParametersExperimental 3D Coordinates
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CCDC 1555902: Experimental Crystal Structure Determination

2018

Related Article: Jade Pratt, Aimee M. Bryan, Michelle Faust, Jessica N. Boynton, Petra Vasko, Brian D. Rekken, Akseli Mansikkamäki, James C. Fettinger, Heikki M. Tuononen, Philip P. Power|2018|Inorg.Chem.|57|6491|doi:10.1021/acs.inorgchem.8b00551

bis[12163236-tetrakis(propan-2-yl)[1121:2331-terphenyl]-22-thiolato]-nickel(ii)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1555896: Experimental Crystal Structure Determination

2018

Related Article: Jade Pratt, Aimee M. Bryan, Michelle Faust, Jessica N. Boynton, Petra Vasko, Brian D. Rekken, Akseli Mansikkamäki, James C. Fettinger, Heikki M. Tuononen, Philip P. Power|2018|Inorg.Chem.|57|6491|doi:10.1021/acs.inorgchem.8b00551

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatesbis[12163236-tetrakis(propan-2-yl)[1121:2331-terphenyl]-22-thiolato]-iron(ii)
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