0000000001307624
AUTHOR
Xavier Sala
Intramolecular proton transfer boosts water oxidation catalyzed by a Ru complex
We introduce a new family of complexes with the general formula [Run(tda)(py)2]m+ (n = 2, m = 0, 1; n = 3, m = 1, 2+; n = 4, m = 2, 32+), with tda2– being [2,2′:6′,2″-terpyridine]-6,6″-dicarboxylate, including complex [RuIV(OH)(tda-κ-N3O)(py)2]+, 4H+, which we find to be an impressive water oxidation catalyst, formed by hydroxo coordination to 32+ under basic conditions. The complexes are synthesized, isolated, and thoroughly characterized by analytical, spectroscopic (UV–vis, nuclear magnetic resonance, electron paramagnetic resonance), computational, and electrochemical techniques (cyclic voltammetry, differential pulse voltammetry, coulometry), …
CCDC 1421699: Experimental Crystal Structure Determination
Related Article: Roc Matheu, Mehmed Z. Ertem, Jordi Benet-Buchholz, Eugenio Coronado, Victor S. Batista, Xavier Sala, and Antoni Llobet|2015|J.Am.Chem.Soc.|137|10786|doi:10.1021/jacs.5b06541
CCDC 1421700: Experimental Crystal Structure Determination
Related Article: Roc Matheu, Mehmed Z. Ertem, Jordi Benet-Buchholz, Eugenio Coronado, Victor S. Batista, Xavier Sala, and Antoni Llobet|2015|J.Am.Chem.Soc.|137|10786|doi:10.1021/jacs.5b06541
CCDC 1421701: Experimental Crystal Structure Determination
Related Article: Roc Matheu, Mehmed Z. Ertem, Jordi Benet-Buchholz, Eugenio Coronado, Victor S. Batista, Xavier Sala, and Antoni Llobet|2015|J.Am.Chem.Soc.|137|10786|doi:10.1021/jacs.5b06541