0000000001307662

AUTHOR

G.c. Papavassiliou

showing 4 related works from this author

Hybrid Molecular Materials Based upon Organic π-Electron Donors and Inorganic Metal Complexes. Conducting Salts of Bis(ethylenediseleno)tetrathiafulv…

2002

Abstract The synthesis, structure and physical characterization of three new radical salts formed by the organic donor bis(ethylenediseleno)tetrathiafulvalene (BEDS-TTF or BEST) and the paramagnetic hexacyanoferrate(III) anion [Fe(CN)6]3− or the photochromic nitroprusside anion [Fe(CN)5NO]2− are reported: (BEST)4[Fe(CN)6] (1), (BEST)3[Fe(CN)6]2·H2O (2) and (BEST)2[Fe(CN)5NO] (3). Salts 1 and 3 show a layered structure with alternating organic (β–type packing) and inorganic slabs. Salt 2 shows an original interpenetrated structure probably due to the unprecedented presence of (BEST)2+ dications. The three salts are semiconductors although salt 1 exhibits a high room temperature conductivity …

chemistry.chemical_classificationBicyclic moleculeInorganic chemistrySalt (chemistry)Crystal structureCondensed Matter PhysicsMolecular electronic transitionElectronic Optical and Magnetic MaterialsInorganic ChemistryMetalCrystallographychemistry.chemical_compoundOctahedronchemistryvisual_artMaterials ChemistryCeramics and Compositesvisual_art.visual_art_mediumMoleculePhysical and Theoretical ChemistryTetrathiafulvaleneJournal of Solid State Chemistry
researchProduct

CCDC 183751: Experimental Crystal Structure Determination

2003

Related Article: M.Clemente-Leon, E.Coronado, J.R.Galan-Mascaros, C.Gimenez-Saiz, C.J.Gomez-Garcia, J.M.Fabre, G.A.Mousdis, G.C.Papavassiliou|2002|J.Solid State Chem.|168|616|doi:10.1006/jssc.2002.9759

Space GroupCrystallographybis(bis(ethylenediseleno)tetrathiafulvalene) nitrosyl-pentacyanoferrate(iii)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 183749: Experimental Crystal Structure Determination

2003

Related Article: M.Clemente-Leon, E.Coronado, J.R.Galan-Mascaros, C.Gimenez-Saiz, C.J.Gomez-Garcia, J.M.Fabre, G.A.Mousdis, G.C.Papavassiliou|2002|J.Solid State Chem.|168|616|doi:10.1006/jssc.2002.9759

Space GroupCrystallographyCrystal SystemCrystal Structuretetrakis(bis(ethylenediseleno)tetrathiafulvalene) hexacyanoferrate(iii)Cell ParametersExperimental 3D Coordinates
researchProduct

CCDC 183750: Experimental Crystal Structure Determination

2003

Related Article: M.Clemente-Leon, E.Coronado, J.R.Galan-Mascaros, C.Gimenez-Saiz, C.J.Gomez-Garcia, J.M.Fabre, G.A.Mousdis, G.C.Papavassiliou|2002|J.Solid State Chem.|168|616|doi:10.1006/jssc.2002.9759

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstetrakis(bis(ethylenediseleno)tetrathiafulvalene) hexacyanoferrate(iii) hemihydrateExperimental 3D Coordinates
researchProduct