0000000001307991

AUTHOR

Antonio Leyva−pérez

showing 4 related works from this author

Highly Efficient MOF-Driven Silver Subnanometer Clusters for the Catalytic Buchner Ring Expansion Reaction

2022

The preparation of novel efficient catalysts-that could be applicable in industrially important chemical processes-has attracted great interest. Small subnanometer metal clusters can exhibit outstanding catalytic capabilities, and thus, research efforts have been devoted, recently, to synthesize novel catalysts bearing such active sites. Here, we report the gram-scale preparation of Ag2subnanometer clusters within the channels of a highly crystalline three-dimensional anionic metal-organic framework, with the formula [Ag2]@AgNa{Ni[Cu(Mempba)]}·48HO [Mempba= N,N′-2,4,6-trimethyl-1,3-phenylenebis(oxamate)]. The resulting crystalline solid catalyst-fully characterized with the help of single-c…

Inorganic ChemistryPhysical and Theoretical ChemistryInorganic Chemistry
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CCDC 2155456: Experimental Crystal Structure Determination

2022

Related Article: Estefanía Tiburcio, Yongkun Zheng, Marta Mon, Nuria Martín, Jesús Ferrando−Soria, Donatella Armentano, Antonio Leyva−Pérez, Emilio Pardo|2022|Inorg.Chem.|61|11796|doi:10.1021/acs.inorgchem.2c01508

catena-[sodium(i) silver(i) silver(0) tris(mu-24-bis{[carboxylato(oxidanidyl)methylidene]amino}-135-trimethylbenzene)-triaqua-tri-copper(ii)-di-nickel(ii) hydrate]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2155455: Experimental Crystal Structure Determination

2022

Related Article: Estefanía Tiburcio, Yongkun Zheng, Marta Mon, Nuria Martín, Jesús Ferrando−Soria, Donatella Armentano, Antonio Leyva−Pérez, Emilio Pardo|2022|Inorg.Chem.|61|11796|doi:10.1021/acs.inorgchem.2c01508

catena-[sodium(i) silver(i) silver(0) tris(mu-24-bis{[carboxylato(oxidanidyl)methylidene]amino}-135-trimethylbenzene)-triaqua-tri-copper(ii)-di-nickel(ii) hydrate]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1841425: Experimental Crystal Structure Determination

2018

Related Article: Marta Mon, Rosa Adam, Jesús Ferrando−Soria, Avelino Corma, Donatella Armentano, Emilio Pardo, and Antonio Leyva−Pérez|2018|ACS Catalysis|8|10401|doi:10.1021/acscatal.8b03228

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[(hexa-aqua-ruthenium) hexakis(mu-24-bis((carboxylato(oxido)methylidene)amino)-135-trimethylbenzene)-hexa-aqua-hexa-copper-tetra-nickel unknown solvate hydrate]Cell ParametersExperimental 3D Coordinates
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