0000000001308013

AUTHOR

William K. Myers

showing 4 related works from this author

A crystalline radical cation derived from Thiele’s hydrocarbon with redox range beyond 1 V

2021

Thiele’s hydrocarbon occupies a central role as an open-shell platform for new organic materials, however little is known about its redox behaviour. While recent synthetic approaches involving symmetrical carbene substitution of the CPh2 termini yield isolable neutral/dicationic analogues, the intervening radical cations are much more difficult to isolate, due to narrow compatible redox ranges (typically  1 V), permitting its isolation in crystalline form. Further single-electron oxidation affords borenium dication 12+, thereby establishing an organoboron redox system fully characterized in all three redox states. We perceive that this strategy can be extended to other transient organic rad…

Electronic materialsRadicalScienceGeneral Physics and Astronomy010402 general chemistryPhotochemistryvapaat radikaalit01 natural sciencesRedoxArticleGeneral Biochemistry Genetics and Molecular Biologychemistry.chemical_compoundhapetus-pelkistysreaktiochemistry.chemical_classificationRange (particle radiation)kemiallinen synteesiMultidisciplinary010405 organic chemistryQkationitfood and beveragesGeneral Chemistryhiilivedyt0104 chemical sciencesDicationHydrocarbonRadical ionchemistryYield (chemistry)CarbeneInorganic chemistry
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CCDC 2063254: Experimental Crystal Structure Determination

2021

Related Article: Ying Kai Loh, Petra Vasko, Caitil��n McManus, Andreas Heilmann, William K. Myers, Simon Aldridge|2021|Nat.Commun.|12|7052|doi:10.1038/s41467-021-27104-y

Space GroupCrystallography2-(1-{13-bis[26-bis(propan-2-yl)phenyl]-13-dihydro-2H-132-diazaborol-2-yl}pyridin-1-ium-4-yl)-13-bis[26-bis(propan-2-yl)phenyl]-23-dihydro-1H-imidazol-2-ylium bis(hexakis(fluoro)-antimony) dichloromethane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2063252: Experimental Crystal Structure Determination

2021

Related Article: Ying Kai Loh, Petra Vasko, Caitil��n McManus, Andreas Heilmann, William K. Myers, Simon Aldridge|2021|Nat.Commun.|12|7052|doi:10.1038/s41467-021-27104-y

Space GroupCrystallographyCrystal System{N1N2-bis[26-bis(propan-2-yl)phenyl]ethene-12-diaminato}{4-[13-bis(246-trimethylphenyl)imidazol-2-ylidene]-14-dihydropyridin-1-ium-1-ylidene}boronCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2063253: Experimental Crystal Structure Determination

2021

Related Article: Ying Kai Loh, Petra Vasko, Caitil��n McManus, Andreas Heilmann, William K. Myers, Simon Aldridge|2021|Nat.Commun.|12|7052|doi:10.1038/s41467-021-27104-y

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters1-{13-bis[26-bis(propan-2-yl)phenyl]-13-dihydro-2H-132-diazaborol-2-yl}-4-{13-bis[26-bis(propan-2-yl)phenyl]-13-dihydro-2H-imidazol-2-ylidene}-14-dihydropyridin-1-ium radical hexakis(fluoro)-antimonyExperimental 3D Coordinates
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