0000000001308128
AUTHOR
D. Gavaskar
Crystal structure of 5′′-(4-chlorobenzylidene)-4′-(4-chlorophenyl)-1′-methyltrispiro[acenapthylene-1,2′-pyrrolidine-3′,1′′-cyclohexane-3′′,2′′′-[1,3]dioxane]-2(1H),6′′-dione
In the title compound, C36H29Cl2NO4, two spiro links connect the methyl-substituted pyrrolidine ring to the acenaphthylene and cyclohexanone rings. The cyclohexanone ring is further connected to the dioxalane ring by a third spiro junction. The five-membered ring of the acenaphthylen-1-one ring system adopts a flattened envelope conformation, with the ketonic C atom as the flap, whereas the dioxalane and pyrrolidine rings each have a twist conformation. The cyclohexenone ring assumes a boat conformation. An intramolecular C—H...O hydrogen-bond interaction is present. In the crystal, molecules are linked by non-classical C—H...O hydrogen bonds, forming chains extending parallel to theaaxis.
Crystal structure of 1-ferrocenyl-2-(4-methyl-benzo-yl)spiro-[11H-pyrrolidizine-3,11'-indeno[1,2-b]quinoxaline].
In the title compound the four-fused-rings system is approximately planar and the pyrrolidine rings of the pyrrolidizine fragment adopt a twist conformation. In the crystal, molecules are linked by C—H⋯O hydrogen bonds and C—H⋯π interactions, forming double-chains parallel to the c axis.
Crystal structure of 5′′-benzylidene-1′-methyl-4′-phenyltrispiro[acenaphthylene-1,2′-pyrrolidine-3′,1′′-cyclohexane-3′′,2′′′-[1,3]dioxane]-2,6′′-dione
In the title trispiro compound, both the methyl-substituted pyrrolidine and dioxalane rings adopt a twist conformation. The cyclopentanone ring of the acenapthylen-1-one system adopts flattened envelope conformation, and the cyclohexanone attached to the dioxalane ring adopts boat conformation. In the crystal, centrosymmetrically related molecules are linked into dimers forming rings of (10) graph-set motif, which are further connected into chains parallel to the b axis by C—H⋯O contacts forming rings of (8) graph-set motif.
CCDC 1427830: Experimental Crystal Structure Determination
Related Article: K. Chandralekha, D. Gavaskar, A.R. Sureshbabu, S. Lakshmi|2015|Acta Crystallogr.,Sect.E:Cryst.Commun.|71|o814|doi:10.1107/S2056989015018034
CCDC 1454097: Experimental Crystal Structure Determination
Related Article: K. Chandralekha, D. Gavaskar, A.R. Sureshbabu, S. Lakshmi|2016|Acta Crystallogr.,Sect.E:Cryst.Commun.|72|387|doi:10.1107/S2056989016002875
CCDC 1017369: Experimental Crystal Structure Determination
Related Article: K. Chandralekha, D. Gavaskar, A.R. Sureshbabu, S. Lakshmi|2014|Acta Crystallogr.,Sect.E:Struct.Rep.Online|70|124|doi:10.1107/S1600536814017644
CCDC 1546766: Experimental Crystal Structure Determination
Related Article: K. Chandralekha, D. Gavaskar, A.R. Sureshbabu, S. Lakshmi|2017|IUCrData|2|x170639|doi:10.1107/S2414314617006393