Author: B. Valtancoli

0000000001308267

AUTHOR

B. Valtancoli

Polyfunctional recognition of pyridinedicarboxylate anions with macrocyclic polyamine receptors containing heteroaromatic groups.

The interaction of the biologically relevant anions deriving from the six pyridinedicarboxylic acids (H2PDC) with two macrocyclic receptors containing a pentamine chain and a bipyridine (1) or a phenanthroline (2) moiety, as well as with the aliphatic analogue [21]aneN7 (3), was studied by means of spectroscopic methods (UV-vis, NMR) and potentiometric titrations affording the stability constants of the adducts formed. All three receptors form stable complexes with the substrates thanks to the formation of several salt bridges and hydrogen bond contacts, as observed in the crystal structure of the H8[3(2,6-PDC)4] x H2O x 0.5 EtOH solid compound. Additional pi-stacking interactions between t…

research product

CCDC 787307: Experimental Crystal Structure Determination

Related Article: C.Bazzicalupi, A.Bencini, S.Ciattini, F.Denat, P.Desogere, C.Goze, I.Matera, B.Valtancoli|2010|Dalton Trans.|39|11643|doi:10.1039/c0dt00948b

research product

CCDC 787306: Experimental Crystal Structure Determination

Related Article: C.Bazzicalupi, A.Bencini, S.Ciattini, F.Denat, P.Desogere, C.Goze, I.Matera, B.Valtancoli|2010|Dalton Trans.|39|11643|doi:10.1039/c0dt00948b

research product

CCDC 787305: Experimental Crystal Structure Determination

Related Article: C.Bazzicalupi, A.Bencini, S.Ciattini, F.Denat, P.Desogere, C.Goze, I.Matera, B.Valtancoli|2010|Dalton Trans.|39|11643|doi:10.1039/c0dt00948b

research product

CCDC 711041: Experimental Crystal Structure Determination

Related Article: C.Bazzicalupi, A.Bencini, A.Bianchi, C.Borri, A.Danesi, E.Garcia-Espana, C.Giorgi, B.Valtancoli|2008|J.Org.Chem.|73|8286|doi:10.1021/jo801366w

research product

CCDC 787308: Experimental Crystal Structure Determination

Related Article: C.Bazzicalupi, A.Bencini, S.Ciattini, F.Denat, P.Desogere, C.Goze, I.Matera, B.Valtancoli|2010|Dalton Trans.|39|11643|doi:10.1039/c0dt00948b

research product

CCDC 787304: Experimental Crystal Structure Determination

Related Article: C.Bazzicalupi, A.Bencini, S.Ciattini, F.Denat, P.Desogere, C.Goze, I.Matera, B.Valtancoli|2010|Dalton Trans.|39|11643|doi:10.1039/c0dt00948b

research product

PEPhysical Sciences and Engineering
- PE2Fundamental Constituents of Matter
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LSLife Sciences
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