Author: Christoph Gamer

0000000001308446

AUTHOR

Christoph Gamer

A SIM-MOF: Three-Dimensional Organisation of Single-Ion Magnets with Anion-Exchange Capabilities

The formation of a metal-organic framework (MOF) with nodes that have single-molecule magnet (SMM) behaviour has been achieved by using mononuclear lanthanoid analogues, also known as single-ion magnets (SIMs), which enormously simplifies the challenging issue of making SMM-MOFs. Here we present a rational design of a family of MOFs, [Ln(bipyNO)4](TfO)3⋅x solvent (Ln=Tb (1); Dy (2); Ho (3); Er (4); TfO=triflate), in which the lanthanoid centres have an square-antiprismatic coordination environment suitable for SIM behaviour. Magnetic measurements confirm the existence of slow magnetic relaxation typical of SMMs, which has been rationalised by means of a radial effective charge model. In add…

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Metallacrown Complexes Reaching the Nanosize Regime

Abstract The chapter discusses the merit of metallacrown complexes to achieve multifunctional and multidimensional molecular materials. It introduces basic design strategies for discrete metallacrown complexes and discusses the predictability of molecular properties. Thereafter, it reviews two of the most outstanding molecular properties of metallacrown complexes, namely, the magnetic and luminescence characteristics. Most interestingly, for metallacrown complexes, such properties could be combined in one single molecule, giving rise to stable “multifunctional” molecular materials. Moreover, MCs are suitable building blocks to construct multidimensional coordination polymers. The chapter pr…

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Inside Cover: A SIM-MOF: Three-Dimensional Organisation of Single-Ion Magnets with Anion-Exchange Capabilities (Chem. Eur. J. 34/2014)

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CCDC 987661: Experimental Crystal Structure Determination

Related Article: José J. Baldoví, Eugenio Coronado, Alejandro Gaita-Ariño, Christoph Gamer, Mónica Giménez-Marqués, Guillermo Mínguez Espallargas|2014|Chem.-Eur.J.|20|10695|doi:10.1002/chem.201402255

research product

CCDC 987659: Experimental Crystal Structure Determination

Related Article: José J. Baldoví, Eugenio Coronado, Alejandro Gaita-Ariño, Christoph Gamer, Mónica Giménez-Marqués, Guillermo Mínguez Espallargas|2014|Chem.-Eur.J.|20|10695|doi:10.1002/chem.201402255

research product

CCDC 987658: Experimental Crystal Structure Determination

Related Article: José J. Baldoví, Eugenio Coronado, Alejandro Gaita-Ariño, Christoph Gamer, Mónica Giménez-Marqués, Guillermo Mínguez Espallargas|2014|Chem.-Eur.J.|20|10695|doi:10.1002/chem.201402255

research product

CCDC 987660: Experimental Crystal Structure Determination

Related Article: José J. Baldoví, Eugenio Coronado, Alejandro Gaita-Ariño, Christoph Gamer, Mónica Giménez-Marqués, Guillermo Mínguez Espallargas|2014|Chem.-Eur.J.|20|10695|doi:10.1002/chem.201402255

research product

CCDC 987656: Experimental Crystal Structure Determination

Related Article: José J. Baldoví, Eugenio Coronado, Alejandro Gaita-Ariño, Christoph Gamer, Mónica Giménez-Marqués, Guillermo Mínguez Espallargas|2014|Chem.-Eur.J.|20|10695|doi:10.1002/chem.201402255

research product

CCDC 987655: Experimental Crystal Structure Determination

Related Article: José J. Baldoví, Eugenio Coronado, Alejandro Gaita-Ariño, Christoph Gamer, Mónica Giménez-Marqués, Guillermo Mínguez Espallargas|2014|Chem.-Eur.J.|20|10695|doi:10.1002/chem.201402255

research product

CCDC 987657: Experimental Crystal Structure Determination

Related Article: José J. Baldoví, Eugenio Coronado, Alejandro Gaita-Ariño, Christoph Gamer, Mónica Giménez-Marqués, Guillermo Mínguez Espallargas|2014|Chem.-Eur.J.|20|10695|doi:10.1002/chem.201402255

research product

CCDC 987654: Experimental Crystal Structure Determination

Related Article: José J. Baldoví, Eugenio Coronado, Alejandro Gaita-Ariño, Christoph Gamer, Mónica Giménez-Marqués, Guillermo Mínguez Espallargas|2014|Chem.-Eur.J.|20|10695|doi:10.1002/chem.201402255

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PEPhysical Sciences and Engineering
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