Author: Xiao-feng Zhang

0000000001308569

AUTHOR

Xiao-feng Zhang

Magnetic behavior control in niccolite structural metal formate frameworks [NH2(CH3)2][Fe(III)M(II)(HCOO)6] (M = Fe, Mn, and Co) by varying the divalent metal ions.

By changing template cation but introducing trivalent iron ions in the known niccolite structural metal formate frameworks, three complexes formulated [NH(2)(CH(3))(2)][Fe(III)M(II)(HCOO)(6)] (M = Fe for 1, Mn for 2, and Co for 3) were synthesized and magnetically characterized. The variation in the compositions of the complexes leads to three different complexes: mixed-valent complex 1, heterometallic but with the same spin state complex 2, and heterometallic heterospin complex 3. The magnetic behaviors are closely related to the divalent metal ions used. Complex 1 exhibits negative magnetization assigned as Neel N-Type ferrimagnet, with an asymmetric magnetization reversal in the hysteres…

research product

CCDC 816221: Experimental Crystal Structure Determination

Related Article: Jiong-Peng Zhao, Bo-Wen Hu, F.Lloret, Jun Tao, Qian Yang, Xiao-Feng Zhang, Xian-He Bu|2010|Inorg.Chem.|49|10390|doi:10.1021/ic1014863

research product

CCDC 816222: Experimental Crystal Structure Determination

Related Article: Jiong-Peng Zhao, Bo-Wen Hu, F.Lloret, Jun Tao, Qian Yang, Xiao-Feng Zhang, Xian-He Bu|2010|Inorg.Chem.|49|10390|doi:10.1021/ic1014863

research product

CCDC 816224: Experimental Crystal Structure Determination

Related Article: Jiong-Peng Zhao, Bo-Wen Hu, F.Lloret, Jun Tao, Qian Yang, Xiao-Feng Zhang, Xian-He Bu|2010|Inorg.Chem.|49|10390|doi:10.1021/ic1014863

research product

CCDC 816223: Experimental Crystal Structure Determination

Related Article: Jiong-Peng Zhao, Bo-Wen Hu, F.Lloret, Jun Tao, Qian Yang, Xiao-Feng Zhang, Xian-He Bu|2010|Inorg.Chem.|49|10390|doi:10.1021/ic1014863

research product

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