Author: Kaplan Kirakci

0000000001308729

AUTHOR

Kaplan Kirakci

A Series of Ultra-Efficient Blue Borane Fluorophores

13 pags., 14 figs., 5 tabs.

research product

Effect of Iodination on the Photophysics of the Laser Borane anti-B18H22: Generation of Efficient Photosensitizers of Oxygen

Treatment of the laser borane anti-B18H22 (compound 1) with iodine in ethanol gives the monoiodinated derivative 7-I-anti-B18H21 (compound 2) in 67% yield, or, by reaction with iodine or ICl in the presence of AlCl3 in dichloromethane, the diiodinated derivative 4,4'-I2-anti-B18H20 (compound 3) in 85% yield. On excitation with 360 nm light, both compounds 2 and 3 give strong green phosphorescent emissions (λmax = 525 nm, ΦL = 0.41 and λmax = 545 nm, ΦL = 0.71 respectively) that are quenched by dioxygen to produce O2(1Δg) singlet oxygen with quantum yields of ΦΔ = 0.52 and 0.36 respectively. Similarly strong emissions can be stimulated via the nonlinear process of two-photon absorption when …

research product

CCDC 2009109: Experimental Crystal Structure Determination

Related Article: Jonathan Bould, Kamil Lang, Kaplan Kirakci, Luis Cerdán, Daniel Roca-Sanjuán, Antonio Francés-Monerris, William Clegg, Paul G. Waddell, Marcel Fuciman, Tomáš Polívka, Michael G. S. Londesborough|2020|Inorg.Chem.|59|17058|doi:10.1021/acs.inorgchem.0c02277

research product

CCDC 2009108: Experimental Crystal Structure Determination

Related Article: Jonathan Bould, Kamil Lang, Kaplan Kirakci, Luis Cerdán, Daniel Roca-Sanjuán, Antonio Francés-Monerris, William Clegg, Paul G. Waddell, Marcel Fuciman, Tomáš Polívka, Michael G. S. Londesborough|2020|Inorg.Chem.|59|17058|doi:10.1021/acs.inorgchem.0c02277

research product

CCDC 2009112: Experimental Crystal Structure Determination

Related Article: Jonathan Bould, Kamil Lang, Kaplan Kirakci, Luis Cerdán, Daniel Roca-Sanjuán, Antonio Francés-Monerris, William Clegg, Paul G. Waddell, Marcel Fuciman, Tomáš Polívka, Michael G. S. Londesborough|2020|Inorg.Chem.|59|17058|doi:10.1021/acs.inorgchem.0c02277

research product

CCDC 2009113: Experimental Crystal Structure Determination

Related Article: Jonathan Bould, Kamil Lang, Kaplan Kirakci, Luis Cerdán, Daniel Roca-Sanjuán, Antonio Francés-Monerris, William Clegg, Paul G. Waddell, Marcel Fuciman, Tomáš Polívka, Michael G. S. Londesborough|2020|Inorg.Chem.|59|17058|doi:10.1021/acs.inorgchem.0c02277

research product

CCDC 1859436: Experimental Crystal Structure Determination

Related Article: Michael G. S. Londesborough, Jiří Dolanský, Jonathan Bould, Jakub Braborec, Kaplan Kirakci, Kamil Lang, Ivana Císařová, Pavel Kubát, Daniel Roca-Sanjuán, Antonio Francés-Monerris, Lenka Slušná, Eva Noskovičová, Dušan Lorenc|2019|Inorg.Chem.|58|10248|doi:10.1021/acs.inorgchem.9b01358

research product

CCDC 2009110: Experimental Crystal Structure Determination

Related Article: Jonathan Bould, Kamil Lang, Kaplan Kirakci, Luis Cerdán, Daniel Roca-Sanjuán, Antonio Francés-Monerris, William Clegg, Paul G. Waddell, Marcel Fuciman, Tomáš Polívka, Michael G. S. Londesborough|2020|Inorg.Chem.|59|17058|doi:10.1021/acs.inorgchem.0c02277

research product

CCDC 2009106: Experimental Crystal Structure Determination

Related Article: Jonathan Bould, Kamil Lang, Kaplan Kirakci, Luis Cerdán, Daniel Roca-Sanjuán, Antonio Francés-Monerris, William Clegg, Paul G. Waddell, Marcel Fuciman, Tomáš Polívka, Michael G. S. Londesborough|2020|Inorg.Chem.|59|17058|doi:10.1021/acs.inorgchem.0c02277

research product

CCDC 2009105: Experimental Crystal Structure Determination

Related Article: Jonathan Bould, Kamil Lang, Kaplan Kirakci, Luis Cerdán, Daniel Roca-Sanjuán, Antonio Francés-Monerris, William Clegg, Paul G. Waddell, Marcel Fuciman, Tomáš Polívka, Michael G. S. Londesborough|2020|Inorg.Chem.|59|17058|doi:10.1021/acs.inorgchem.0c02277

research product

CCDC 2009107: Experimental Crystal Structure Determination

Related Article: Jonathan Bould, Kamil Lang, Kaplan Kirakci, Luis Cerdán, Daniel Roca-Sanjuán, Antonio Francés-Monerris, William Clegg, Paul G. Waddell, Marcel Fuciman, Tomáš Polívka, Michael G. S. Londesborough|2020|Inorg.Chem.|59|17058|doi:10.1021/acs.inorgchem.0c02277

research product

CCDC 1859437: Experimental Crystal Structure Determination

Related Article: Michael G. S. Londesborough, Jiří Dolanský, Jonathan Bould, Jakub Braborec, Kaplan Kirakci, Kamil Lang, Ivana Císařová, Pavel Kubát, Daniel Roca-Sanjuán, Antonio Francés-Monerris, Lenka Slušná, Eva Noskovičová, Dušan Lorenc|2019|Inorg.Chem.|58|10248|doi:10.1021/acs.inorgchem.9b01358

research product

CCDC 2009111: Experimental Crystal Structure Determination

Related Article: Jonathan Bould, Kamil Lang, Kaplan Kirakci, Luis Cerdán, Daniel Roca-Sanjuán, Antonio Francés-Monerris, William Clegg, Paul G. Waddell, Marcel Fuciman, Tomáš Polívka, Michael G. S. Londesborough|2020|Inorg.Chem.|59|17058|doi:10.1021/acs.inorgchem.0c02277

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  - SH8_3Cultural studies and theory, cultural identities and memories, cultural heritage
  - SH8_4Museums, exhibitions, conservation and restoration
  - SH8_5History of art and of architecture
  - SH8_6Architecture, design, craft, creative industries
  - SH8_7Music and musicology; history of music
  - SH8_8Visual and performing arts, screen, arts-based research
  - SH8_9Digital approaches to anthropology, cultural studies and art