Author: Eva Jürgens

0000000001308785

AUTHOR

Eva Jürgens

Synthesis of copper(II) and gold(III) bis(NHC)-pincer complexes

Abstract CuII and AuIII chlorido complexes bearing the bis(NHC) carbazolide pincer ligand (bimca) were synthesized by transmetallation from the respective lithium complex [Li(bimca)] (NHC=N-heterocyclic carbene). In the case of copper, two different molecular structures were obtained depending on the copper source. With Cu(II) chloride the paramagnetic mononuclear [Cu(bimca)Cl] complex is formed and has been characterized by EPR spectroscopy and X-ray structure analysis, while copper(I) chloride leads under oxidation to a dinuclear structure in which two cationic [CuII(bimca)] moieties are bridged by one chlorido ligand. The positive charge is compensated by the [CuCl2]− counter ion, as pro…

research product

CCDC 1492154: Experimental Crystal Structure Determination

Related Article: Eva Jürgens, Oliver Back, Johannes J. Mayer, Katja Heinze, Doris Kunz|2016|Z.Naturforsch.,B:Chem.Sci.|71|1011|doi:10.1515/znb-2016-0158

research product

CCDC 1492153: Experimental Crystal Structure Determination

Related Article: Eva Jürgens, Oliver Back, Johannes J. Mayer, Katja Heinze, Doris Kunz|2016|Z.Naturforsch.,B:Chem.Sci.|71|1011|doi:10.1515/znb-2016-0158

research product

PEPhysical Sciences and Engineering
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LSLife Sciences
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