0000000001308916
AUTHOR
Roberto Fraile
Desulfurization processes of thiosemicarbazonecopper(ii) derivatives in acidic and basic aqueous media
This work provides structural evidence for different desulfurization processes in aqueous solutions of [CuL]+ derivatives (HL = pyridine-2-carbaldehyde thiosemicarbazone). Structural resolution has been achieved for the [{CuL(SH)}2] (1), [CuLCl]2[Cu(pic)2] (pic− = picolinato, pyridine-2-carboxilato) (2) and [Cu(HL)(NCS)](NO3) (4) compounds, together with a derivative of 4 with formula [Cu(HL)(NCS)][Cu(HL)(NCS)0.72(NO3)0.28](NO3)2 (5), whose HS−, pic− and NCS− ligands come from thiosemicarbazone breakage. The behaviour of the [CuL]+ species in basic aqueous solutions or water under reflux has been compared with that exhibited by iron(III), cobalt(III), zinc(II) and lead(II) derivatives of th…
Splash erosion: A review with unanswered questions
66 Pags.- 1 Tabl.- 7 Figs. The definitive version is available at: http://www.sciencedirect.com/science/journal/00128252
CCDC 930871: Experimental Crystal Structure Determination
Related Article: Rubén Gil-García, Roberto Fraile, Bruno Donnadieu, Gotzon Madariaga, Vaidas Januskaitis, Jordi Rovira, Lucía González, Joaquín Borrás, Francisco Javier Arnáiz, Javier García-Tojal|2013|New J.Chem.|37|3568|doi:10.1039/C3NJ00321C
CCDC 930872: Experimental Crystal Structure Determination
Related Article: Rubén Gil-García, Roberto Fraile, Bruno Donnadieu, Gotzon Madariaga, Vaidas Januskaitis, Jordi Rovira, Lucía González, Joaquín Borrás, Francisco Javier Arnáiz, Javier García-Tojal|2013|New J.Chem.|37|3568|doi:10.1039/C3NJ00321C
CCDC 930874: Experimental Crystal Structure Determination
Related Article: Rubén Gil-García, Roberto Fraile, Bruno Donnadieu, Gotzon Madariaga, Vaidas Januskaitis, Jordi Rovira, Lucía González, Joaquín Borrás, Francisco Javier Arnáiz, Javier García-Tojal|2013|New J.Chem.|37|3568|doi:10.1039/C3NJ00321C
CCDC 930873: Experimental Crystal Structure Determination
Related Article: Rubén Gil-García, Roberto Fraile, Bruno Donnadieu, Gotzon Madariaga, Vaidas Januskaitis, Jordi Rovira, Lucía González, Joaquín Borrás, Francisco Javier Arnáiz, Javier García-Tojal|2013|New J.Chem.|37|3568|doi:10.1039/C3NJ00321C
CCDC 930875: Experimental Crystal Structure Determination
Related Article: Rubén Gil-García, Roberto Fraile, Bruno Donnadieu, Gotzon Madariaga, Vaidas Januskaitis, Jordi Rovira, Lucía González, Joaquín Borrás, Francisco Javier Arnáiz, Javier García-Tojal|2013|New J.Chem.|37|3568|doi:10.1039/C3NJ00321C