0000000001308932
AUTHOR
C. Baldoli
Rh(I) Coordination Chemistry of Chiral α-Aminophosphine(η6-arene)chromium Tricarbonyl Ligands
The diastereoselective addition of Ph(2)PH to the chiral ortho-substituted eta(6)-benzaldimine complexes (eta(6)-o-X-C(6)H(4)CH=NAr)Cr(CO)(3) (1, X = MeO, Ar = p-C(6)H(4)OMe; 2, X = Cl, Ar = Ph) leads to the formation of the corresponding chiral aminophosphines (alpha-P,N) Ph(2)P-CH(Ar(1))-NHAr(2) (3, Ar(1) = o-C(6)H(4)(OCH(3))[Cr(CO)(3)], Ar(2) = p-C(6)H(4)OCH(3); 4, Ar(1) = o-C(6)H(4)Cl[Cr(CO)(3)], Ar(2) = Ph) in equilibrium with the starting materials. The uncomplexed benzaldimine (o-ClC(6)H(4)CH=NPh), 2', analogously produces an equilibrium amount of the corresponding aminophosphine Ph(2)P-CH(Ar(1))-NHAr(2) (4', Ar(1) = o-C(6)H(4)Cl, Ar(2) = Ph). Depending on the equilibrium constant, t…
CCDC 209632: Experimental Crystal Structure Determination
Related Article: J.-M.Camus, J.Andrieu, R.Poli, P.Richard, C.Baldoli, S.Maiorana|2003|Inorg.Chem.|42|2384|doi:10.1021/ic025588k
CCDC 209633: Experimental Crystal Structure Determination
Related Article: J.-M.Camus, J.Andrieu, R.Poli, P.Richard, C.Baldoli, S.Maiorana|2003|Inorg.Chem.|42|2384|doi:10.1021/ic025588k