0000000001308984

AUTHOR

Hongshan Ke

showing 2 related works from this author

A triple-bridged azido-Cu(II) chain compound fine-tuned by mixed carboxylate/ethanol linkers displays slow-relaxation and ferromagnetic order: synthe…

2014

A new azido-Cu(II) compound, [Cu(4-fba)(N3)(C2H5OH)] (4-fba = 4-fluorobenzoic acid) (1), has been synthesized and characterized. The X-ray crystal structure analysis demonstrates that only one crystallographically independent Cu(II) ion in the asymmetric unit of 1 exhibits a stretched octahedral geometry in which two azido N atoms and two carboxylic O atoms locate in the equatorial square, while two ethanol O atoms occupy the apical positions, forming a 1D Cu(II) chain with an alternating triple-bridge of EO-azido, syn,syn-carboxylate, and μ2-ethanol. The title compound consists of ferromagnetically interacting ferromagnetic chains, which exhibit ferromagnetic order (Tc = 7.0 K). The strong…

Inorganic Chemistrychemistry.chemical_compoundCrystallographychemistryFerromagnetismStereochemistryHydrogen bondOctahedral molecular geometryRelaxation (NMR)MoleculeCarboxylateCrystal structureIonDalton transactions (Cambridge, England : 2003)
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CCDC 980967: Experimental Crystal Structure Determination

2014

Related Article: Xiangyu Liu, Sanping Chen, Thais Grancha, Emilio Pardo, Hongshan Ke, Bing Yin, Qing Wei, Gang Xie, Shengli Gao|2014|Dalton Trans.|43|15359|doi:10.1039/C4DT02195A

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-[(mu-azido)-(mu-ethanol)-(mu-4-fluorobenzoato)-copper(ii)]
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