Author: Tamara Topala

0000000001308993

AUTHOR

Tamara Topala

Photoinduced and Self‐Activated Nuclease Activity of Copper(II) Complexes with N ‐(Quinolin‐8‐yl)quinolin‐8‐sulfonamide – DNA and Bovine Serum Albumin Binding

Two CuII complexes with a new quinoline sulfonamide derivative and phenanthroline (phen), [Cu(QSQ)(phen)]ClO4·0.5H2O (1) and [Cu(QSQ)(phen)(H2O)]ClO4 (2) [HQSQ = N-(quinolin-8-yl)quinolin-8-sulfonamide], have been synthesized and physicochemically characterized. Single-crystal X-ray diffraction studies have revealed a highly distorted trigonal-bipyramidal structure for 1 (τ = 0.68) and an almost perfect trigonal-bipyramidal geometry for 2 (τ = 0.92). DNA binding studies, which were performed by thermal denaturation, viscometry, fluorescence spectroscopy, and cyclic voltammetry, indicated a partial intercalation of 1 with Kapp = 2.45 × 106 M–1. The nuclease activity of 1 was investigated upo…

research product

CCDC 1407215: Experimental Crystal Structure Determination

Related Article: Alejandro Pascual-Álvarez, Tamara Topala, Francisco Estevan, Francisca Sanz and Gloria Alzuet-Piña|2016|Eur.J.Inorg.Chem.||982|doi:10.1002/ejic.201501469

research product

CCDC 1407214: Experimental Crystal Structure Determination

Related Article: Alejandro Pascual-Álvarez, Tamara Topala, Francisco Estevan, Francisca Sanz and Gloria Alzuet-Piña|2016|Eur.J.Inorg.Chem.||982|doi:10.1002/ejic.201501469

research product

PEPhysical Sciences and Engineering
- PE2Fundamental Constituents of Matter
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LSLife Sciences
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