Author: Fanfang Pan

0000000001309102

AUTHOR

Fanfang Pan

Expanding the Size of Catecholesters - Modified Ligands for the Hierarchical Assembly of Dinuclear Titanium(IV) Helicates

Five 2,3-dihydroxybenzoic acid derivatives 1 – 5 were used as starting materials to obtain the corresponding methyl and ethyl esters. Those were applied as ligands in the hierarchical self-assembly of lithium-bridged dinuclear titanium(IV) complexes 1a–4a, 1b–3b, and 5b. The equilibria between the mononuclear triscatecholate complexes (monomer) and the dinuclear helicates (dimer) were observed by 1H NMR spectroscopy in [D6]DMSO and [D4]MeOH at room temperature.

research product

CCDC 1407855: Experimental Crystal Structure Determination

Related Article: David Van Craen, Marita de Groot, Markus Albrecht, Fanfang Pan and Kari Rissanen|2015|Z.Anorg.Allg.Chem.|641|2222|doi:10.1002/zaac.201500543

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PEPhysical Sciences and Engineering
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