0000000001309167

AUTHOR

Verena Arens

showing 7 related works from this author

Intramolecularly Coordinated Bis(crown ether)-Substituted Organotin Halides as Ditopic Salt Receptors

2013

The synthesis of the bis(crown ether)-substituted organostannanes X2Sn(CH2-[16]-crown-5)2 (3, X = I; 4, X = Br; 5, X = Cl; 6, X = F) and X2Sn(CH2-[13]-crown-4)2 (10, X = I; 11, X = Br; 12, X = F) is reported. The compounds have been characterized by 1H, 13C, 19F, and 119Sn NMR spectroscopy, elemental analyses, and electrospray ionization mass spectrometry (ESI-MS). Single-crystal X-ray diffraction analyses reveal a distorted-octahedral cis,cis,trans configuration of the tin atoms in compounds 4–6 and 10–12 as a result of intramolecular O→Sn coordination. The ability of the host molecules to form mono- and ditopic complexes with various halide salts in different solvents, including water, ha…

chemistry.chemical_classificationStereochemistryElectrospray ionizationOrganic Chemistrychemistry.chemical_elementHalideSalt (chemistry)Nuclear magnetic resonance spectroscopyMedicinal chemistryInorganic ChemistrychemistryIntramolecular forceMoleculePhysical and Theoretical ChemistryTinCrown etherOrganometallics
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CCDC 902177: Experimental Crystal Structure Determination

2013

Related Article: Verena Arens, Christina Dietz, Dieter Schollmeyer, and Klaus Jurkschat|2013|Organometallics|32|2775|doi:10.1021/om400216z

Space GroupCrystallographyCrystal SystemCrystal Structurebis(Iodo)-bis(14710-tetraoxacylcotridec-12-ylmethyl)-tin(iv)Cell ParametersExperimental 3D Coordinates
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CCDC 902179: Experimental Crystal Structure Determination

2013

Related Article: Verena Arens, Christina Dietz, Dieter Schollmeyer, and Klaus Jurkschat|2013|Organometallics|32|2775|doi:10.1021/om400216z

Space GroupCrystallographyDifluoro-bis(14710-tetraoxacylcotridec-12-ylmethyl)-tin(iv)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 902174: Experimental Crystal Structure Determination

2013

Related Article: Verena Arens, Christina Dietz, Dieter Schollmeyer, and Klaus Jurkschat|2013|Organometallics|32|2775|doi:10.1021/om400216z

Dibromo-bis((1471013-pentaoxacyclohexadec-15-yl)methyl)-tin(iv)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 902178: Experimental Crystal Structure Determination

2013

Related Article: Verena Arens, Christina Dietz, Dieter Schollmeyer, and Klaus Jurkschat|2013|Organometallics|32|2775|doi:10.1021/om400216z

Space GroupCrystallographyDibromo-bis(14710-tetraoxacylcotridec-12-ylmethyl)-tin(iv)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 902175: Experimental Crystal Structure Determination

2013

Related Article: Verena Arens, Christina Dietz, Dieter Schollmeyer, and Klaus Jurkschat|2013|Organometallics|32|2775|doi:10.1021/om400216z

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersDichloro-bis((1471013-pentaoxacyclohexadec-15-yl)methyl)-tin(iv)Experimental 3D Coordinates
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CCDC 902176: Experimental Crystal Structure Determination

2013

Related Article: Verena Arens, Christina Dietz, Dieter Schollmeyer, and Klaus Jurkschat|2013|Organometallics|32|2775|doi:10.1021/om400216z

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersDifluoro-bis((1471013-pentaoxacyclohexadec-15-yl)methyl)-tin(iv)Experimental 3D Coordinates
researchProduct