0000000001309191

AUTHOR

Okan Deniz

showing 2 related works from this author

On-surface Synthesis of a Chiral Graphene Nanoribbon with Mixed Edge Structure.

2020

Abstract Chiral graphene nanoribbons represent an important class of graphene nanomaterials with varying combinations of armchair and zigzag edges conferring them unique structure‐dependent electronic properties. Here, we describe the on‐surface synthesis of an unprecedented cove‐edge chiral GNR with a benzo‐fused backbone on a Au(111) surface using 2,6‐dibromo‐1,5‐diphenylnaphthalene as precursor. The initial precursor self‐assembly and the formation of the chiral GNRs upon annealing are revealed, along with a relatively small electronic bandgap of approximately 1.6 eV, by scanning tunnelling microscopy and spectroscopy.

Band gapAnnealing (metallurgy)530 Physics010402 general chemistry01 natural sciencesBiochemistrygraphene nanoribbonNanomaterialslaw.inventionlawchiral edge540 Chemistrypolycyclic aromatic hydrocarbonon-surface synthesisSpectroscopyQuantum tunnelling010405 organic chemistryChemistryGraphenescanning tunneling microscopy and spectroscopyCommunicationOrganic ChemistryGeneral ChemistryCommunications0104 chemical sciencesZigzagChemical physics570 Life sciences; biologyGraphene nanoribbonsChemistry, an Asian journal
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CCDC 2021698: Experimental Crystal Structure Determination

2020

Related Article: Ashok Keerthi, Carlos Sánchez‐Sánchez, Okan Deniz, Pascal Ruffieux, Dieter Schollmeyer, Xinliang Feng, Akimitsu Narita, Roman Fasel, Klaus Müllen|2020|Chem.Asian J.|15|3807|doi:10.1002/asia.202001008

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters26-dibromo-15-diphenylnaphthaleneExperimental 3D Coordinates
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