0000000001309262

AUTHOR

Yurii S. Bibik

showing 2 related works from this author

Thermochromic Meltable Materials with Reverse Spin Transition Controlled by Chemical Design

2020

International audience; We report a series of meltable FeII complexes, which, depending on the length of aliphatic chains, display abrupt forward low‐spin to high‐spin transition or unprecedented melting‐triggered reverse high‐spin to low‐spin transition on temperature rise. The reverse spin transition is perfectly reproducible on thermal cycling and the obtained materials are easily processable in the form of thin film owing to their soft‐matter nature. We found that the discovered approach represents a potentially generalizable new avenue to control both the location in temperature and the direction of the spin transition in meltable compounds.

Phase transitionMaterials scienceBistabilitySpin transitionsSpin transition02 engineering and technologyTemperature cycling010402 general chemistry01 natural sciencesCatalysisSpin crossover[CHIM.COOR]Chemical Sciences/Coordination chemistrySoft matterThin filmThermochromismCondensed matter physics010405 organic chemistryReverse spin transitionGeneral MedicineGeneral Chemistry021001 nanoscience & nanotechnologySpin crossover0104 chemical sciencesCondensed Matter::Strongly Correlated ElectronsSoft matter0210 nano-technology
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CCDC 1994888: Experimental Crystal Structure Determination

2020

Related Article: Francisco‐Javier Valverde‐Muñoz, Maksym Seredyuk, M. Carmen Muñoz, Gábor Molnár, Yurii S. Bibik, José Antonio Real|2020|Angew.Chem.,Int.Ed.|59|18632|doi:10.1002/anie.202006453

Space GroupCrystallographybis{345-tris(hexyloxy)-N-[1-(pyrimidin-2-yl)propylidene]benzene-1-carbohydrazonato}-iron(ii)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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