0000000001309318
AUTHOR
Minzhi Jiang
showing 3 related works from this author
Iodine Clathrated: A Solid‐State Analogue of the Iodine–Starch Complex
2019
Co-crystallizing iodine with a simple dicationic salt (1,8-diammoniumoctane chloride) results in the clathration of the iodine (I2 ) molecules inside trigonal and hexagonal helical channels of the crystal lattice with 72 wt % overall I2 loading. The I2 inside the bigger trigonal channel forms a I-I⋅⋅⋅I-I⋅⋅⋅I-I halogen-bonded infinite helical chain, while the I2 in the smaller hexagonal channel is disordered. In both channels the I2 interaction with the channel wall happens through I-I⋅⋅⋅Cl- halogen bonds. The helical channels in the crystal lattice are constructed via the strong charge-assisted H2 N+ H⋅⋅⋅Cl- hydrogen bonds between the dications and the chloride anions. The structure shows a…
Iodine Clathrated : A Solid-State Analog of the Iodine-Starch Complex
2019
Co-crystallizing iodine with a simple dicationic salt (1,8- diammoniumoctane chloride) results in the clathration of the iodine (I2) molecules inside trigonal and hexagonal helical channels of the crystal lattice with 72 wt% overall I2 loading. The I2 inside the bigger trigonal channel forms a I-I•••I-I•••I-I halogen-bonded infinite helical chain, while the I2 in the smaller hexagonal channel is disordered. In both channels the I2 interaction with the channel wall happens through I-I•••Cl- halogen bonds. The helical channels in the crystal lattice are constructed via the strong charge-assisted H2N+ -H•••Cl- hydrogen bonds between the dications and the chloride anions. The structure shows a …
CCDC 1895019: Experimental Crystal Structure Determination
2019
Related Article: Kari Rissanen, Fangfang Pan, Yingchun Chen, Siyu Li, Minzhi Jiang|2019|Chem.-Eur.J.|25|7485|doi:10.1002/chem.201901734