0000000001309321
AUTHOR
Naz Ugur
Strongly Red-Emissive Molecular Ruby [Cr(bpmp)2]3+ Surpasses [Ru(bpy)3]2+
Gaining chemical control over the thermodynamics and kinetics of photoexcited states is paramount to an efficient and sustainable utilization of photoactive transition metal complexes in a plethora of technologies. In contrast to energies of charge transfer states described by spatially separated orbitals, the energies of spin-flip states cannot straightforwardly be predicted as Pauli repulsion and the nephelauxetic effect play key roles. Guided by multireference quantum chemical calculations, we report a novel highly luminescent spin-flip emitter with a quantum chemically predicted blue-shifted luminescence. The spin-flip emission band of the chromium complex [Cr(bpmp)2]3+ (bpmp = 2,6-bis(…
CCDC 1989536: Experimental Crystal Structure Determination
Related Article: Florian Reichenauer, Cui Wang, Christoph Förster, Pit Boden, Naz Ugur, Ricardo Báez-Cruz, Jens Kalmbach, Luca M. Carrella, Eva Rentschler, Charusheela Ramanan, Gereon Niedner-Schatteburg, Markus Gerhards, Michael Seitz, Ute Resch-Genger, Katja Heinze|2021|J.Am.Chem.Soc.|143|11843|doi:10.1021/jacs.1c05971
CCDC 2083757: Experimental Crystal Structure Determination
Related Article: Florian Reichenauer, Cui Wang, Christoph Förster, Pit Boden, Naz Ugur, Ricardo Báez-Cruz, Jens Kalmbach, Luca M. Carrella, Eva Rentschler, Charusheela Ramanan, Gereon Niedner-Schatteburg, Markus Gerhards, Michael Seitz, Ute Resch-Genger, Katja Heinze|2021|J.Am.Chem.Soc.|143|11843|doi:10.1021/jacs.1c05971
CCDC 1989537: Experimental Crystal Structure Determination
Related Article: Florian Reichenauer, Cui Wang, Christoph Förster, Pit Boden, Naz Ugur, Ricardo Báez-Cruz, Jens Kalmbach, Luca M. Carrella, Eva Rentschler, Charusheela Ramanan, Gereon Niedner-Schatteburg, Markus Gerhards, Michael Seitz, Ute Resch-Genger, Katja Heinze|2021|J.Am.Chem.Soc.|143|11843|doi:10.1021/jacs.1c05971