0000000001309431

AUTHOR

Yvonne Rechkemmer

Synthesis, structural characterization and magnetic behaviour of a family of [CoIII2LnIII2] butterfly compounds

We have successfully prepared and structurally characterized a family of butterfly-like [Co2 IIILn2 III] complexes where all magnetic properties are due to the Ln(iii) ions. The complexes with Ln = Tb(1), Dy(2), Ho(3), Er(4) and Yb(5) are iso-structural. An exception is the complex with Ln = Gd(6) which strings in a one dimensional chain. The structural similarity together with the high tendency of the crystallites to align under an applied magnetic field allowed an overall DC magnetic data treatment to extract phenomenological crystal field parameters and hence to determine the ground state multiplet energy level splitting. The Dy(iii) member is the only one showing slow relaxation of magn…

research product

CCDC 1489635: Experimental Crystal Structure Determination

Related Article: Alejandro V. Funes, Luca Carrella, Yvonne Rechkemmer, Joris van Slageren, Eva Rentschler, Pablo Alborés|2017|Dalton Trans.|46|3400|doi:10.1039/C6DT04713K

research product

CCDC 1489636: Experimental Crystal Structure Determination

Related Article: Alejandro V. Funes, Luca Carrella, Yvonne Rechkemmer, Joris van Slageren, Eva Rentschler, Pablo Alborés|2017|Dalton Trans.|46|3400|doi:10.1039/C6DT04713K

research product

CCDC 1489634: Experimental Crystal Structure Determination

Related Article: Alejandro V. Funes, Luca Carrella, Yvonne Rechkemmer, Joris van Slageren, Eva Rentschler, Pablo Alborés|2017|Dalton Trans.|46|3400|doi:10.1039/C6DT04713K

research product

CCDC 1489637: Experimental Crystal Structure Determination

Related Article: Alejandro V. Funes, Luca Carrella, Yvonne Rechkemmer, Joris van Slageren, Eva Rentschler, Pablo Alborés|2017|Dalton Trans.|46|3400|doi:10.1039/C6DT04713K

research product

CCDC 1489638: Experimental Crystal Structure Determination

Related Article: Alejandro V. Funes, Luca Carrella, Yvonne Rechkemmer, Joris van Slageren, Eva Rentschler, Pablo Alborés|2017|Dalton Trans.|46|3400|doi:10.1039/C6DT04713K

research product