0000000001309434
AUTHOR
Carla Martínez-benito
Influence of the coligand in the magnetic properties of a series of copper(ii)–phenylmalonate complexes
This work presents a series of layered systems based on phenylmalonate-containing copper(II) complexes and different coligands. Eight compounds [Cu(L)(Phmal)]n where L = pyrimidine (pym, 1) pyrazine (pyz, 2), 3-cyanopyridine (3-CNpy, 3), 4-cyanopyridine (4-CNpy, 4), 3-fluoropyridine (3-Fpy, 5), 3-chloropyridine (3-Clpy, 6), 3-bromopyridine (3-Brpy, 7) and 3-iodopyridine (3-Ipy, 8), have been synthesized and magneto-structurally characterized. The coligands selected not only modify the coordination environment of the metal ion, blocking or extending the polymerization, but also interact with the phenyl ring of the phenylmalonate ligand and dramatically affect the crystal packing through weak…
CCDC 996269: Experimental Crystal Structure Determination
Related Article: Jorge Pasán, Joaquín Sanchiz, Óscar Fabelo, Laura Cañadillas-Delgado, Mariadel Déniz, Pau Díaz-Gallifa, Carla Martínez-Benito, Francesc Lloret, Miguel Julve, Catalina Ruiz-Pérez|2014|CrystEngComm|16|8106|doi:10.1039/C4CE00834K
CCDC 996270: Experimental Crystal Structure Determination
Related Article: Jorge Pasán, Joaquín Sanchiz, Óscar Fabelo, Laura Cañadillas-Delgado, Mariadel Déniz, Pau Díaz-Gallifa, Carla Martínez-Benito, Francesc Lloret, Miguel Julve, Catalina Ruiz-Pérez|2014|CrystEngComm|16|8106|doi:10.1039/C4CE00834K
CCDC 996271: Experimental Crystal Structure Determination
Related Article: Jorge Pasán, Joaquín Sanchiz, Óscar Fabelo, Laura Cañadillas-Delgado, Mariadel Déniz, Pau Díaz-Gallifa, Carla Martínez-Benito, Francesc Lloret, Miguel Julve, Catalina Ruiz-Pérez|2014|CrystEngComm|16|8106|doi:10.1039/C4CE00834K
CCDC 996274: Experimental Crystal Structure Determination
Related Article: Jorge Pasán, Joaquín Sanchiz, Óscar Fabelo, Laura Cañadillas-Delgado, Mariadel Déniz, Pau Díaz-Gallifa, Carla Martínez-Benito, Francesc Lloret, Miguel Julve, Catalina Ruiz-Pérez|2014|CrystEngComm|16|8106|doi:10.1039/C4CE00834K
CCDC 996272: Experimental Crystal Structure Determination
Related Article: Jorge Pasán, Joaquín Sanchiz, Óscar Fabelo, Laura Cañadillas-Delgado, Mariadel Déniz, Pau Díaz-Gallifa, Carla Martínez-Benito, Francesc Lloret, Miguel Julve, Catalina Ruiz-Pérez|2014|CrystEngComm|16|8106|doi:10.1039/C4CE00834K
CCDC 996273: Experimental Crystal Structure Determination
Related Article: Jorge Pasán, Joaquín Sanchiz, Óscar Fabelo, Laura Cañadillas-Delgado, Mariadel Déniz, Pau Díaz-Gallifa, Carla Martínez-Benito, Francesc Lloret, Miguel Julve, Catalina Ruiz-Pérez|2014|CrystEngComm|16|8106|doi:10.1039/C4CE00834K