Author: Adam Pikul

0000000001309444

AUTHOR

Adam Pikul

Polar metal–formate frameworks templated with 1,2-diaminoethane–water assemblies showing ferromagnetic and ferroelectric properties

A set of five novel formate frameworks templated with assemblies comprising diprotonated 1,2-diaminoethane (DAE) and a water molecule of the formula: [NH3(CH2)2NH3]M2(HCOO)6·H2O, where M = Mg, Mn, Co, Ni, Zn, has been synthesized. Four compounds crystallize in the polar R3 space group and one in the chiral P6322 space group (Ni-analog) at room temperature. The polyammonium–water assemblies, mutually joined by hydrogen bonds, fill the cavities of the frameworks and are disordered in the three latter compounds. Additional disorder is found in the Ni-sample as the DAE2+–H2O couple is placed in a special position on the 63 screw axis. IR spectroscopy provides evidence of proton dynamic disorder…

research product

CCDC 1551124: Experimental Crystal Structure Determination

Related Article: Monika Trzebiatowska, Bartosz Zarychta, Adam Pikul, Mirosław Mączka, Paulina Peksa, Ryszard Poprawski|2017|Phys.Chem.Chem.Phys.(PCCP)|19|16749|doi:10.1039/C7CP02301D

research product

CCDC 1537667: Experimental Crystal Structure Determination

Related Article: Monika Trzebiatowska, Bartosz Zarychta, Adam Pikul, Mirosław Mączka, Paulina Peksa, Ryszard Poprawski|2017|Phys.Chem.Chem.Phys.(PCCP)|19|16749|doi:10.1039/C7CP02301D

research product

CCDC 1551125: Experimental Crystal Structure Determination

Related Article: Monika Trzebiatowska, Bartosz Zarychta, Adam Pikul, Mirosław Mączka, Paulina Peksa, Ryszard Poprawski|2017|Phys.Chem.Chem.Phys.(PCCP)|19|16749|doi:10.1039/C7CP02301D

research product

CCDC 1551123: Experimental Crystal Structure Determination

Related Article: Monika Trzebiatowska, Bartosz Zarychta, Adam Pikul, Mirosław Mączka, Paulina Peksa, Ryszard Poprawski|2017|Phys.Chem.Chem.Phys.(PCCP)|19|16749|doi:10.1039/C7CP02301D

research product

CCDC 1537668: Experimental Crystal Structure Determination

Related Article: Monika Trzebiatowska, Bartosz Zarychta, Adam Pikul, Mirosław Mączka, Paulina Peksa, Ryszard Poprawski|2017|Phys.Chem.Chem.Phys.(PCCP)|19|16749|doi:10.1039/C7CP02301D

research product

PEPhysical Sciences and Engineering
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