0000000001309516
AUTHOR
Albert Gutiérrez
Polypyridyl-functionalizated alkynyl gold(i) metallaligands supported by tri- and tetradentate phosphanes
A series of alkynyl gold(I) tri and tetratopic metallaligands of the type [Au3(CuC-R)3(μ3-triphosphane)] (R = 2,2'-bipyridin-5-yl or C10H7N2, 2,2':6',2''-terpyridin-4-yl or C15H10N3; triphosphane = 1,1,1-tris(diphenylphosphanyl) ethane or triphos, 1,3,5-tris(diphenylphosphanyl)benzene or triphosph) and [Au4(CuC-R)4 (μ4-tetraphosphane)] (R = C10H7N2, C15H10N3; tetraphosphane = tetrakis(diphenylphosphanylmethyl)methane or tetraphos, 1,2,3,5-tetrakis(diphenylphosphanyl)benzene or tpbz, tetrakis(diphenylphosphaneylmethyl)-1,2- ethylenediamine or dppeda) were obtained in moderate to good yields. All complexes could be prepared by a Q4 reaction between the alkynyl gold(I) polymeric species [Au(Cu…
Base-assisted synthesis of 4-pyridinate gold(I) metallaligands: a study of their use in self-assembly reactions
Made available in DSpace on 2021-06-25T12:16:58Z (GMT). No. of bitstreams: 0 Previous issue date: 2021-05-06 Ministerio de Economia y Competitividad (MINECO/FEDER) of Spain Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) The synthesis of di- and tritopic gold(I) metallaligands of the type [(Au4-py)(2)(mu(2)-diphosphane)] (diphosphane = bis(diphenylphosphanyl)isopropane or dppip (1), 1,2-bis(diphenylphosphanyl)ethane or dppe (2), 1,3-bis(diphenylphosphanyl)propane or dppp (3) and 1,4-bis(diphenylphosphanyl)butane or dppb (4)) and [(Au4-py)(3)(mu(3)-triphosphane)] (triphosphane = 1,1,1-tris(diphenylphosph…
CCDC 2000612: Experimental Crystal Structure Determination
Related Article: Montserrat Ferrer, Albert Gutiérrez, Manuel Martínez, Cristiana Da Silva, Adelino V. G. Netto, Laura Rodríguez, Guillermo Romo-Islas, Fangfang Pan, Kari Rissanen|2021|Dalton Trans.|50|8154|doi:10.1039/D1DT00402F
CCDC 1561541: Experimental Crystal Structure Determination
Related Article: Montserrat Ferrer, Leticia Giménez, Albert Gutiérrez, João Carlos Lima, Manuel Martínez, Laura Rodríguez, Avelino Martín, Rakesh Puttreddy, Kari Rissanen|2017|Dalton Trans.|46|13920|doi:10.1039/C7DT02732J
CCDC 1559283: Experimental Crystal Structure Determination
Related Article: Montserrat Ferrer, Leticia Giménez, Albert Gutiérrez, João Carlos Lima, Manuel Martínez, Laura Rodríguez, Avelino Martín, Rakesh Puttreddy, Kari Rissanen|2017|Dalton Trans.|46|13920|doi:10.1039/C7DT02732J
CCDC 2000611: Experimental Crystal Structure Determination
Related Article: Montserrat Ferrer, Albert Gutiérrez, Manuel Martínez, Cristiana Da Silva, Adelino V. G. Netto, Laura Rodríguez, Guillermo Romo-Islas, Fangfang Pan, Kari Rissanen|2021|Dalton Trans.|50|8154|doi:10.1039/D1DT00402F
CCDC 2000613: Experimental Crystal Structure Determination
Related Article: Montserrat Ferrer, Albert Gutiérrez, Manuel Martínez, Cristiana Da Silva, Adelino V. G. Netto, Laura Rodríguez, Guillermo Romo-Islas, Fangfang Pan, Kari Rissanen|2021|Dalton Trans.|50|8154|doi:10.1039/D1DT00402F
CCDC 2000614: Experimental Crystal Structure Determination
Related Article: Montserrat Ferrer, Albert Gutiérrez, Manuel Martínez, Cristiana Da Silva, Adelino V. G. Netto, Laura Rodríguez, Guillermo Romo-Islas, Fangfang Pan, Kari Rissanen|2021|Dalton Trans.|50|8154|doi:10.1039/D1DT00402F