0000000001309520
AUTHOR
Guillermo Romo-islas
Heterometallic Au(I)–Cu(I) Clusters : Luminescence Studies and 1O2 Production
Two different organometallic gold(I) compounds containing naphthalene and phenanthrene as fluorophores and 2-pyridyldiphenylphosphane as the ancillary ligand were synthesized (compounds 1 with naphthalene and 2 with phenanthrene). They were reacted with three different copper(I) salts with different counterions (PF6–, OTf–, and BF4–; OTf = triflate) to obtain six Au(I)/Cu(I) heterometallic clusters (compounds 1a–c for naphthalene derivatives and 2a–c for phenanthrene derivatives). The heterometallic compounds present red pure room-temperature phosphorescence in both solution, the solid state, and air-equilibrated samples, as a difference with the dual emission recorded for the gold(I) precu…
Base-assisted synthesis of 4-pyridinate gold(I) metallaligands: a study of their use in self-assembly reactions
Made available in DSpace on 2021-06-25T12:16:58Z (GMT). No. of bitstreams: 0 Previous issue date: 2021-05-06 Ministerio de Economia y Competitividad (MINECO/FEDER) of Spain Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) The synthesis of di- and tritopic gold(I) metallaligands of the type [(Au4-py)(2)(mu(2)-diphosphane)] (diphosphane = bis(diphenylphosphanyl)isopropane or dppip (1), 1,2-bis(diphenylphosphanyl)ethane or dppe (2), 1,3-bis(diphenylphosphanyl)propane or dppp (3) and 1,4-bis(diphenylphosphanyl)butane or dppb (4)) and [(Au4-py)(3)(mu(3)-triphosphane)] (triphosphane = 1,1,1-tris(diphenylphosph…
CCDC 2000612: Experimental Crystal Structure Determination
Related Article: Montserrat Ferrer, Albert Gutiérrez, Manuel Martínez, Cristiana Da Silva, Adelino V. G. Netto, Laura Rodríguez, Guillermo Romo-Islas, Fangfang Pan, Kari Rissanen|2021|Dalton Trans.|50|8154|doi:10.1039/D1DT00402F
CCDC 2000611: Experimental Crystal Structure Determination
Related Article: Montserrat Ferrer, Albert Gutiérrez, Manuel Martínez, Cristiana Da Silva, Adelino V. G. Netto, Laura Rodríguez, Guillermo Romo-Islas, Fangfang Pan, Kari Rissanen|2021|Dalton Trans.|50|8154|doi:10.1039/D1DT00402F
CCDC 2000613: Experimental Crystal Structure Determination
Related Article: Montserrat Ferrer, Albert Gutiérrez, Manuel Martínez, Cristiana Da Silva, Adelino V. G. Netto, Laura Rodríguez, Guillermo Romo-Islas, Fangfang Pan, Kari Rissanen|2021|Dalton Trans.|50|8154|doi:10.1039/D1DT00402F
CCDC 2000614: Experimental Crystal Structure Determination
Related Article: Montserrat Ferrer, Albert Gutiérrez, Manuel Martínez, Cristiana Da Silva, Adelino V. G. Netto, Laura Rodríguez, Guillermo Romo-Islas, Fangfang Pan, Kari Rissanen|2021|Dalton Trans.|50|8154|doi:10.1039/D1DT00402F