0000000001309548

AUTHOR

Amit Chakraborty

showing 5 related works from this author

S-shaped decanuclear heterometallic [Ni8Ln2] complexes [Ln(iii) = Gd, Tb, Dy and Ho]: theoretical modeling of the magnetic properties of the gadolini…

2014

The reaction of 8-quinolinol-2-carboaldoxime (LH2) with Ni(II) and Ln(III) salts afforded the heterometallic decanuclear compounds [Ni8Dy2(μ3-OH)2(L)8(LH)2(H2O)6](ClO4)2·16H2O (1), [Ni8Gd2(μ3-OH)2(L)8(LH)2(H2O)4(MeOH)2](NO3)2·12H2O (2), [Ni8Ho2(μ3-OH)2(L)8(LH)2(H2O)4(MeOH)2](ClO4)2·2MeOH·12H2O (3) and [Ni8Tb2 (μ3-OH)2(L)8(LH)2(MeOH)4(OMe)2]·2CH2Cl2·8H2O (4). While compounds 1-3 are dicationic, compound 4 is neutral. These compounds possess an S-shaped architecture and comprise a long chain of metal ions bound to each other. In all the complexes, the eight Ni(II) and two Ln(III) ions of the multimetallic ensemble are hold together by two μ3-OH, eight dianionic (L(2-)) and two monoanionic oxi…

StereochemistryGadoliniumMetal ions in aqueous solutionchemistry.chemical_elementOximeIonInorganic Chemistrychemistry.chemical_compoundMolecular wireCrystallographychemistryFerromagnetismAntiferromagnetismDerivative (chemistry)Dalton Trans.
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CCDC 986609: Experimental Crystal Structure Determination

2014

Related Article: Sakiat Hossain, Sourav Das, Amit Chakraborty, Francesc Lloret, Joan Cano, Emilio Pardo, Vadapalli Chandrasekhar|2014|Dalton Trans.|43|10164|doi:10.1039/C4DT00465E

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametershexakis(mu~4~-2-[(oxidoimino)methyl]quinolin-8-olato)-bis(mu~3~-2-[(oxidoimino)methyl]quinolin-8-olato)-bis(mu~3~-hydroxo)-bis(2-[(hydroxyimino)methyl]quinolin-8-olate)-hexa-aqua-di-dysprosium-octa-nickel diperchlorate hexadecahydrateExperimental 3D Coordinates
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CCDC 986612: Experimental Crystal Structure Determination

2014

Related Article: Sakiat Hossain, Sourav Das, Amit Chakraborty, Francesc Lloret, Joan Cano, Emilio Pardo, Vadapalli Chandrasekhar|2014|Dalton Trans.|43|10164|doi:10.1039/C4DT00465E

Space GroupCrystallographyCrystal SystemCrystal Structurehexakis(mu~4~-2-[(oxidoimino)methyl]quinolin-8-olato)-bis(mu~3~-2-[(oxidoimino)methyl]quinolin-8-olato)-bis(mu~3~-hydroxo)-bis(2-[(hydroxyimino)methyl]quinolin-8-olate)-dimethoxo-tetrakis(methanol)-di-terbium-octa-nickel dichloromethane solvate octahydrateCell ParametersExperimental 3D Coordinates
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CCDC 986611: Experimental Crystal Structure Determination

2014

Related Article: Sakiat Hossain, Sourav Das, Amit Chakraborty, Francesc Lloret, Joan Cano, Emilio Pardo, Vadapalli Chandrasekhar|2014|Dalton Trans.|43|10164|doi:10.1039/C4DT00465E

Space GroupCrystallographyCrystal Systemhexakis(mu~4~-2-[(oxidoimino)methyl]quinolin-8-olato)-bis(mu~3~-2-[(oxidoimino)methyl]quinolin-8-olato)-bis(mu~3~-hydroxo)-bis(2-[(hydroxyimino)methyl]quinolin-8-olate)-dimethanol-tetra-aqua-di-holmium-octa-nickel diperchlorate undecahydrateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 986610: Experimental Crystal Structure Determination

2014

Related Article: Sakiat Hossain, Sourav Das, Amit Chakraborty, Francesc Lloret, Joan Cano, Emilio Pardo, Vadapalli Chandrasekhar|2014|Dalton Trans.|43|10164|doi:10.1039/C4DT00465E

Space GroupCrystallographyhexakis(mu~4~-2-[(oxidoimino)methyl]quinolin-8-olato)-bis(mu~3~-2-[(oxidoimino)methyl]quinolin-8-olato)-bis(mu~3~-hydroxo)-bis(2-[(hydroxyimino)methyl]quinolin-8-olate)-dimethanol-tetra-aqua-di-gadolinium-octa-nickel dinitrate dodecahydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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