Author: Stefania Bertella

0000000001309656

AUTHOR

Stefania Bertella

Anion-Exchange Properties of Trifluoroacetate and Triflate Salts of N-Alkylammonium Resorcinarenes

The synthesis of N-benzyl- and N-cyclohexylammonium resorcinarene trifluoroacetate (TFA) and triflate (OTf) salt receptors was investigated. Solid-state analysis by single-crystal X-ray diffraction revealed that the N-alkylammonium resorcinarene salts (NARSs) with different upper substituents had different cavity sizes and different affinities for anions. Anion-exchange experiments by mixing equimolar amounts of N-benzylammonium resorcinarene trifluoroacetate and N-cyclohexylammonium resorcinarene triflate, as well as N-benzylammonium resorcinarene triflate and N-cyclohexylammonium resorcinarene trifluoroacetate showed that the NARS with flexible benzyl groups preferred the larger OTf anion…

research product

CCDC 1439768: Experimental Crystal Structure Determination

Related Article: Fangfang Pan, Ngong Kodiah Beyeh, Stefania Bertella, Kari Rissanen|2016|Chem.Asian J.|11|782|doi:10.1002/asia.201501335

research product

CCDC 1439767: Experimental Crystal Structure Determination

Related Article: Fangfang Pan, Ngong Kodiah Beyeh, Stefania Bertella, Kari Rissanen|2016|Chem.Asian J.|11|782|doi:10.1002/asia.201501335

research product

CCDC 1439770: Experimental Crystal Structure Determination

Related Article: Fangfang Pan, Ngong Kodiah Beyeh, Stefania Bertella, Kari Rissanen|2016|Chem.Asian J.|11|782|doi:10.1002/asia.201501335

research product

CCDC 1439769: Experimental Crystal Structure Determination

Related Article: Fangfang Pan, Ngong Kodiah Beyeh, Stefania Bertella, Kari Rissanen|2016|Chem.Asian J.|11|782|doi:10.1002/asia.201501335

research product

PEPhysical Sciences and Engineering
- PE2Fundamental Constituents of Matter
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LSLife Sciences
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